School of Advanced Chemical Sciences, Faculty of Basic Sciences, Shoolini University, Solan, HP 173229, India.
Department of Chemistry, College of Science, King Saud University, Saudi Arabia.
Int J Biol Macromol. 2023 Jan 31;226:1284-1308. doi: 10.1016/j.ijbiomac.2022.11.241. Epub 2022 Nov 26.
In recent times, green chemistry or "green world" is a new and effective approach for sustainable environmental remediation. Among all biomaterials, cellulose is a vital material in research and green chemistry. Cellulose is the most commonly used natural biopolymer because of its distinctive and exceptional properties such as reproducibility, cost-effectiveness, biocompatibility, biodegradability, and universality. Generally, coupling cellulose with other nanocomposite materials enhances the properties like porosity and specific surface area. The polymer is environment-friendly, bioresorbable, and sustainable which not only justifies the requirements of a good photocatalyst but boosts the adsorption ability and degradation efficiency of the nanocomposite. Hence, knowing the role of cellulose to enhance photocatalytic activity, the present review is focused on the properties of cellulose and its application in antibiotics, textile dyes, phenol and Cr(VI) reduction, and degradation. The work also highlighted the degradation mechanism of cellulose-based photocatalysts, confirming cellulose's role as a support material to act as a sink and electron mediator, suppressing the charge carrier's recombination rate and enhancing the charge migration ability. The review also covers the latest progressions, leanings, and challenges of cellulose biomaterials-based nanocomposites in the photocatalysis field.
近年来,绿色化学或“绿色世界”是一种可持续环境修复的新的有效方法。在所有生物材料中,纤维素是研究和绿色化学中的重要材料。纤维素是最常用的天然生物聚合物,因为它具有独特和卓越的特性,如可重复性、成本效益、生物相容性、可生物降解性和通用性。通常,将纤维素与其他纳米复合材料结合使用可以提高多孔性和比表面积等特性。该聚合物环保、可生物降解且可持续,这不仅符合良好光催化剂的要求,而且还能提高纳米复合材料的吸附能力和降解效率。因此,鉴于纤维素在增强光催化活性方面的作用,本综述重点介绍了纤维素的性质及其在抗生素、纺织染料、苯酚和 Cr(VI)还原以及降解方面的应用。该工作还强调了基于纤维素的光催化剂的降解机制,证实了纤维素作为一种支撑材料的作用,充当了一个汇和电子介质,抑制了载流子的复合速率并增强了电荷迁移能力。该综述还涵盖了纤维素基纳米复合材料在光催化领域的最新进展、学习和挑战。