Dipartimento di Scienze della Terra, Università di Firenze, Florence I-50121, Italy.
School of Geosciences, University of South Florida, Tampa, FL 33620.
Proc Natl Acad Sci U S A. 2023 Jan 3;120(1):e2215484119. doi: 10.1073/pnas.2215484119. Epub 2022 Dec 27.
We report the discovery of a dodecagonal quasicrystal MnSiCrAlNi-composed of a periodic stacking of atomic planes with quasiperiodic translational order and 12-fold symmetry along the two directions perpendicular to the planes-accidentally formed by an electrical discharge event in an eolian dune in the Sand Hills near Hyannis, Nebraska, United States. The quasicrystal, coexisting with a cubic crystalline phase with composition MnSiNiCrAl, was found in a fulgurite consisting predominantly of fused and melted sand along with traces of melted conductor metal from a nearby downed power line. The fulgurite may have been created by a lightning strike that combined sand with material from downed power line or from electrical discharges from the downed power line alone. Extreme temperatures of at least 1,710 °C were reached, as indicated by the presence of SiO glass in the sample. The dodecagonal quasicrystal is an example of a quasicrystal of any kind formed by electrical discharge, suggesting other places to search for quasicrystals on Earth or in space and for synthesizing them in the laboratory.
我们报告了一种十二面体准晶 MnSiCrAlNi 的发现,它由原子平面的周期性堆积组成,具有准周期性平移序和沿两个垂直于平面的方向的 12 重旋转对称性,这是在美国内布拉斯加州海恩尼斯附近的沙丘中的一次放电事件偶然形成的。准晶与具有组成 MnSiNiCrAl 的立方晶相共存,存在于主要由熔融和熔化的沙子以及附近倒下的输电线的融化导体金属的痕迹组成的玻璃纤维中。玻璃纤维可能是由闪电引起的,闪电将沙子与倒下的输电线的材料或仅来自倒下的输电线的电放电结合在一起。正如样品中存在 SiO 玻璃所表明的那样,温度至少达到了 1710°C。这种十二面体准晶是通过放电形成的任何种类的准晶的一个例子,这表明在地球上或太空中还有其他地方可以寻找准晶,并在实验室中合成它们。