Chen Yu-Jiao, Wu Liang-Tao, Xiao Hang, Sun Xiao-Li, Wan Wen-Ming
Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, People's Republic of China.
College of Environment and Resources Engineering Research Center of Polymer Green Recycling of Ministry of Education Fujian Key Laboratory of Pollution Control & Resource Reuse, Fujian Normal University, Fuzhou, 350007, P. R. China.
Chempluschem. 2023 Jan;88(1):e202200388. doi: 10.1002/cplu.202200388. Epub 2022 Dec 29.
The Barbier reaction, a classical name reaction for carbon-carbon bond formation, has played important roles in organic chemistry for over 120 years. The introduction of the Barbier reaction into polymer chemistry for the development of a novel Barbier polymerization, expands the methodology, monomer, chemical structure and property libraries of polymerization, aggregation-induced emission (AIE) and non-traditional intrinsic luminescence (NTIL). This mini review focuses on Barbier polymerization, including the brief introduction of the history and importance of polymerization methods design and the achievements of Barbier polymerization from molecular design strategies, functionalities and properties. An outlook of Barbier polymerization is also proposed. This mini review on Barbier polymerization therefore may cause inspirations to scientists in different fields.
巴比耶反应是一种用于形成碳 - 碳键的经典命名反应，在有机化学领域已发挥了120多年的重要作用。将巴比耶反应引入聚合物化学以开发新型巴比耶聚合反应，扩展了聚合、聚集诱导发光（AIE）和非传统本征发光（NTIL）的方法、单体、化学结构和性能库。本综述聚焦于巴比耶聚合反应，包括聚合方法设计的历史和重要性的简要介绍，以及从分子设计策略、功能和性能方面阐述巴比耶聚合反应所取得的成果。同时还对巴比耶聚合反应进行了展望。因此，这篇关于巴比耶聚合反应的综述可能会给不同领域的科学家带来启发。
