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新型磁性纳米复合材料 FeO@Saponin/Cu(II) 作为一种有效的可回收催化剂,用于通过 Bett 反应合成氨基烷基萘酚。

New magnetic nanocomposite FeO@Saponin/Cu(II) as an effective recyclable catalyst for the synthesis of aminoalkylnaphthols via Betti reaction.

机构信息

Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran.

Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran.

出版信息

Steroids. 2023 Mar;191:109170. doi: 10.1016/j.steroids.2022.109170. Epub 2022 Dec 29.

DOI:10.1016/j.steroids.2022.109170
PMID:36587779
Abstract

In this research, a new magnetic nanocomposite FeO@Saponin/Cu(II) based on quillaja saponin was prepared and the catalyst structure was characterized thoroughly using FT-IR, EDS, TGA, XRD, VSM, HR-TEM, SEM, ICP, BET analyzes. The catalyst prepared in the three-component synthesis of several Betti bases, 1-(α-aminoalkyl)naphthols, under environmentally friendly conditions was used. The advantage of this reaction is the high efficiency of the products and the short reaction time. Furthermore, FeO@Saponin/Cu(II) nano-catalyst is recoverable magnetically and is reusable for other processes with no reduction in its activity.

摘要

在这项研究中,制备了一种基于皂素的新型磁性纳米复合材料 FeO@Saponin/Cu(II),并使用 FT-IR、EDS、TGA、XRD、VSM、HR-TEM、SEM、ICP 和 BET 分析对催化剂结构进行了全面表征。该催化剂是在环境友好条件下通过几种 Betti 碱、1-(α-氨基烷基)萘酚的三组分合成中制备的。该反应的优点是产物效率高,反应时间短。此外,FeO@Saponin/Cu(II)纳米催化剂可通过磁性回收,并且在其活性没有降低的情况下可用于其他过程的重复使用。

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