一种用于 CO 光还原和咪唑依赖的无水质子传导的多孔 Ti 基金属有机骨架。
A porous Ti-based metal-organic framework for CO photoreduction and imidazole-dependent anhydrous proton conduction.
机构信息
School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo 255049, P. R. China.
Shandong Engineering Research Center of Green and High-value Marine Fine Chemical, Weifang University of Science and Technology, Shouguang, 262700, China.
出版信息
Chem Commun (Camb). 2023 Jan 24;59(8):1070-1073. doi: 10.1039/d2cc06214c.
The anhydrous proton conductivity of Im@IEF-11 resulting from the integration of imidazole and porous IEF-11 has been investigated, and the highest proton conductive value can reach up to 7.64 × 10 S cm. Furthermore, IEF-11 is also developed to reduce CO due to its reasonable structure and suitable energy band, and its CO formation rate is 31.86 μmol g h.
Im@IEF-11 中咪唑基团与多孔 IEF-11 的整合产生了无水质子导电性，最高质子导电值可达到 7.64×10 S cm。此外，IEF-11 还因其合理的结构和适宜的能带而被开发用来还原 CO，其 CO 生成速率为 31.86 μmol g h。
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