Max-Planck-Institut für Quantenoptik, Garching, Germany.
Munich Center for Quantum Science and Technology, Munich, Germany.
Nature. 2023 Jan;613(7944):463-467. doi: 10.1038/s41586-022-05437-y. Epub 2023 Jan 18.
Conventional superconductivity emerges from pairing of charge carriers-electrons or holes-mediated by phonons. In many unconventional superconductors, the pairing mechanism is conjectured to be mediated by magnetic correlations, as captured by models of mobile charges in doped antiferromagnets. However, a precise understanding of the underlying mechanism in real materials is still lacking and has been driving experimental and theoretical research for the past 40 years. Early theoretical studies predicted magnetic-mediated pairing of dopants in ladder systems, in which idealized theoretical toy models explained how pairing can emerge despite repulsive interactions. Here we experimentally observe this long-standing theoretical prediction, reporting hole pairing due to magnetic correlations in a quantum gas of ultracold atoms. By engineering doped antiferromagnetic ladders with mixed-dimensional couplings, we suppress Pauli blocking of holes at short length scales. This results in a marked increase in binding energy and decrease in pair size, enabling us to observe pairs of holes predominantly occupying the same rung of the ladder. We find a hole-hole binding energy of the order of the superexchange energy and, upon increased doping, we observe spatial structures in the pair distribution, indicating repulsion between bound hole pairs. By engineering a configuration in which binding is strongly enhanced, we delineate a strategy to increase the critical temperature for superconductivity.
常规超导性源于通过声子介导的电荷载流子(电子或空穴)配对。在许多非常规超导体中,配对机制被推测为由掺杂反铁磁体中移动电荷的模型所捕获的磁关联介导。然而,对实际材料中潜在机制的确切理解仍然缺乏,并在过去 40 年中推动了实验和理论研究。早期的理论研究预测了梯状系统中掺杂剂的磁介导配对,在该系统中,理想化的理论玩具模型解释了尽管存在排斥相互作用,配对仍如何出现。在这里,我们通过实验观察到了这一长期存在的理论预测,报告了在超冷原子量子气体中由于磁相关性而导致的空穴配对。通过工程设计具有混合维度耦合的掺杂反铁磁梯状结构,我们在短尺度上抑制了空穴的泡利阻塞。这导致结合能显著增加,对大小减小,使我们能够观察到主要占据梯状结构同一梯级的空穴对。我们发现空穴-空穴结合能约为超交换能量,并且在增加掺杂后,我们观察到对分布中的空间结构,表明束缚空穴对之间存在排斥。通过设计一种结合能得到强烈增强的构型,我们制定了一种提高超导临界温度的策略。