Kodaira Felipe Vicente de Paula, Leal Bruno Henrique Silva, Tavares Thayna Fernandes, Quade Antje, Hein Luis Rogerio de Oliveira, Chiappim William, Kostov Konstantin Georgiev
Laboratory of Plasmas and Applications, Department of Physics, Faculty of Engineering and Sciences, São Paulo State University (UNESP), Guaratinguetá, São Paulo 12516-410, Brazil.
Leibniz Institute for Plasma Science and Technology-INP, 17489 Greifswald, Germany.
Polymers (Basel). 2023 Jan 16;15(2):461. doi: 10.3390/polym15020461.
A conical-shaped atmospheric pressure plasma jet (CS-APPJ) was developed to overcome a standard limitation of APPJs, which is their small treatment area. The CS-APPJs increase the treatment area but use the same gas flow. In the present work, polypropylene samples were treated by CS-APPJ and characterized by scanning electron microscope (SEM), the contact angle, Fourier-transformed infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). It was observed that the treatment co-occurs on the face directly in contact with the plasma and on the opposite face (OF) of the samples, i.e., no contact. However, the treatment changed the chemical composition on each side; the OF is rougher than the direct contact face (DCF), probably due to the oxygen groups in excess at the DCF and nitrogen in quantity at the OF. Although simultaneous treatment of both sides of the sample occurs for most atmospheric plasma treatments, this phenomenon is not explored in the literature.
为克服常压等离子体射流(APPJ)的一个标准局限性,即其处理面积小的问题,开发了一种锥形常压等离子体射流(CS-APPJ)。CS-APPJ增加了处理面积,但使用相同的气体流量。在本工作中,用CS-APPJ处理聚丙烯样品,并通过扫描电子显微镜(SEM)、接触角、傅里叶变换红外光谱(FTIR)和X射线光电子能谱(XPS)对其进行表征。观察到处理同时发生在与等离子体直接接触的表面以及样品的相对表面(OF)上,即未接触的表面。然而,处理改变了每一侧的化学成分;OF比直接接触表面(DCF)更粗糙,这可能是由于DCF处过量的氧基团和OF处大量的氮。尽管大多数常压等离子体处理都会同时处理样品的两侧,但文献中并未探讨这一现象。