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基于手性超分子共组装的诱导 CPL 活性材料。

Induced CPL-Active Materials Based on Chiral Supramolecular Co-Assemblies.

机构信息

Nanjing University, State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing, 210023, P. R. China.

Nanjing University of Posts and Telecommunications, Key Laboratory for Organic Electronics &, Information Displays (KLOEID) and, Institute of Advanced Materials, National Synergistic Innovation Center for, Advanced Materials (SICAM), Nanjing, 210023, P. R. China.

出版信息

Chemistry. 2023 Apr 18;29(22):e202204039. doi: 10.1002/chem.202204039. Epub 2023 Mar 14.

Abstract

Circularly polarized luminescence (CPL) has attracted much interest due to its potential applications on chiral photonic techniques and optoelectronic materials science. As known, dissymmetry factor (g ) of CPL is one essential factor for evaluating the features of CPL-active materials. Much attention has focused on how to increase the g value, which is one of the most important issues for CPL practical applications. Recently, more and more works have demonstrated that chiral supramolecular could provide the significant strategy to improve the g value through the orderly helical superstructure of chiral building blocks. Normally, this kind of chiral supramolecular assembly process can be accompanied by chirality transfer and induction mechanism, which can promote the amplification effect on the induced CPL of achiral dyes. In this review, we fully summarized recent advances on the induced CPL-active materials of chiral supramolecular co-assemblies, their applications in circularly polarized organic light-emitting diodes (CP-OLEDs) and current challenges.

摘要

圆偏振发光(CPL)由于其在手性光子技术和光电材料科学中的潜在应用而引起了广泛关注。众所周知,CPL 的不对称因子(g 因子)是评估 CPL 活性材料特性的一个重要因素。人们一直关注如何提高 g 值,这是 CPL 实际应用的最重要问题之一。最近,越来越多的工作表明,手性超分子可以通过手性构建块的有序螺旋超结构提供提高 g 值的重要策略。通常,这种手性超分子组装过程伴随着手性转移和诱导机制,从而可以增强对非手性染料的诱导 CPL 的放大效应。在本文中,我们全面总结了手性超分子共组装的诱导 CPL 活性材料的最新进展及其在圆偏振有机发光二极管(CP-OLED)中的应用和当前挑战。

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