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基于皮兹模型的砷酸钠在氢氧化钠溶液中的溶解行为。

The solubility behavior of sodium arsenate in NaOH solution based on the Pitzer model.

作者信息

Song Kun, Lv Xiaodong, Shi Jing, Yi Yu, Xin Yuntao

机构信息

College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China.

Jiangxi Huagan Nerin Precious Metals Technology Co., Ltd, Yichun 331100, China.

出版信息

Heliyon. 2023 Jan 6;9(1):e12849. doi: 10.1016/j.heliyon.2023.e12849. eCollection 2023 Jan.

Abstract

Alkaline leaching is an effective method for dealing with arsenic-containing resources. Arsenic is dissolved in an alkaline solution in the form of arsenate, but the lack of relevant basic data has caused difficulties in the theoretical analysis during production and research. The dissolution behavior of arsenic in the solution was systematically studied in this paper. The solubility behavior of the self-made sodium arsenate in water and NaOH solution were measured. The research on sodium arsenate solution was carried out to obtain the quasi-solubility product using the Pitzer model, and the effect of temperature and NaOH concentration on the solubility and quasi-solubility product of sodium arsenate was clarified.

摘要

碱性浸出是处理含砷资源的一种有效方法。砷以砷酸盐的形式溶解在碱性溶液中,但缺乏相关基础数据给生产和研究过程中的理论分析带来了困难。本文系统地研究了砷在溶液中的溶解行为。测定了自制砷酸钠在水和氢氧化钠溶液中的溶解行为。利用皮兹模型对砷酸钠溶液进行研究以获得准溶度积,并阐明了温度和氢氧化钠浓度对砷酸钠溶解度和准溶度积的影响。

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