Bissette Andrew J
Communications Chemistry, .
Commun Chem. 2021 May 27;4(1):80. doi: 10.1038/s42004-021-00519-w.
Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity.
诸如铝之类的路易斯酸添加剂能够使过渡金属催化剂展现出迷人的新反应活性，但几乎没有催化中间体得到过表征。如今，一种镍-铝钳形配合物为金属转移反应提供了新的机理见解以及新的反应活性潜力。
