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可生物降解塑料及其对指纹检测方法的影响。

Biodegradable plastics and their impact on fingermark detection methods.

作者信息

Woodward Harrison, Moret Sébastien, Chadwick Scott

机构信息

University of Technology Sydney, Centre for Forensic Science, Broadway, NSW 2007, Australia.

University of Technology Sydney, Centre for Forensic Science, Broadway, NSW 2007, Australia; School of Human Sciences, College of Science and Engineering, University of Derby, United Kingdom.

出版信息

Forensic Sci Int. 2023 Mar;344:111571. doi: 10.1016/j.forsciint.2023.111571. Epub 2023 Jan 20.

Abstract

The use of plastics is extremely prevalent in society, with most individuals likely to handle several plastic items per day. It is therefore not surprising that many exhibits recovered from the scene of a crime are plastics, which are processed and examined for traces such as fingermarks. Societal trends have been pushing towards more environmentally friendly products with alternatives to traditional disposable plastics becoming increasingly available. These alternate plastics have different chemical compositions and physical properties, which may impact fingermark development for these substrates. As most detection techniques are known to be substrate-dependent, it is crucial to review current methods and procedures to examine how effective they are on new materials. The aim of this research was to assess a range of fingermark detection techniques on biodegradable plastics and provide recommendations for the preferred technique. First, the prevalence of these materials in the Australian market was evaluated. Over 40 different plastics obtained within the Sydney area were then divided into six broad categories using consumer information in combination with ATR-FTIR spectroscopy analysis. Following this, selected plastics from each category were used as substrates for the fingermark development study. In total, 6480 fingermark specimens were collected as split marks, to form 2160 fingermark comparisons. Each substrate was then developed with four fingermark detection techniques suitable for plastic substrates: cyanoacrylate (CA) fuming, vacuum metal deposition (VMD), powder suspensions (PS), and single metal deposition (SMD). SMD resulted in the most consistent development method across all tested substrates. VMD was able to successfully develop fingermarks on polyethylene-based plastics, but led to poorer results on alternative plastics, while CA fuming and PS were notably more dependent on the surface texture. This research was successful in confirming that biodegradable plastics do in fact have an impact on fingermark development techniques commonly applied on traditional plastics and recommendations have been formed to aid in operational contexts to improve the potential to recover latent fingermarks from biodegradable plastics.

摘要

塑料在社会中的使用极为普遍,大多数人每天可能会接触到多个塑料制品。因此,从犯罪现场找回的许多证物是塑料制品也就不足为奇了,这些塑料制品会被处理并检查是否有指纹等痕迹。社会趋势一直在推动使用更环保的产品,传统一次性塑料的替代品越来越多。这些替代塑料具有不同的化学成分和物理特性,这可能会影响在这些基材上指纹的显现。由于大多数检测技术已知依赖于基材,因此审查当前的方法和程序以检查它们对新材料的有效性至关重要。本研究的目的是评估一系列用于可生物降解塑料的指纹检测技术,并为首选技术提供建议。首先,评估了这些材料在澳大利亚市场的普及程度。然后,利用消费者信息并结合衰减全反射傅里叶变换红外光谱(ATR-FTIR)分析,将在悉尼地区获得的40多种不同塑料分为六大类。在此之后,从每个类别中选择的塑料用作指纹显现研究的基材。总共收集了6480个指纹样本作为分裂痕迹,形成2160个指纹比较。然后,每种基材都用四种适用于塑料基材的指纹检测技术进行显现:氰基丙烯酸酯(CA)熏蒸、真空金属沉积(VMD)、粉末悬浮液(PS)和单金属沉积(SMD)。SMD在所有测试基材上产生了最一致的显现方法。VMD能够成功地在聚乙烯基塑料上显现指纹,但在替代塑料上效果较差,而CA熏蒸和PS明显更依赖于表面纹理。这项研究成功地证实,可生物降解塑料确实会对通常应用于传统塑料的指纹显现技术产生影响,并已形成相关建议,以帮助在实际操作中提高从可生物降解塑料上提取潜在指纹的可能性。

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