UV assisted synthesis of folic acid functionalized ZnO-Ag hexagonal nanoprisms for efficient catalytic reduction of Cr and 4-nitrophenol.

Chemical-based syntheses of metallic nanoparticles (MNPs) has become a major topic of research exploration in the field of nanotechnology. The utilization of folic acid (FA) as stabilizing and capping agent has been reported as a novel route for the synthesis of bimetallic nanomaterials. The present study includes novel research and brief discussion about preparation of UV light assisted ZnO-Ag nanobars (NBs) using FA as stabilizing agent and its catalytic applications on the reduction of organic pollutants (4-NP and Cr) using NBs as a catalyst alongwith ascorbic acid (AA). Analytical techniques including UV-visible spectroscopy, XRD, SEM, EDX and FT-IR were used for the characterizing synthesized ZnO-Ag NBs. Hexagonal structure of ZnO-Ag NBs were found having crystallite size 5.6 nm and SEM studies revealed the nanobar width 33.2 nm and length 133.5 nm. The prepared ZnO-Ag NBs were tested for their catalytic activity for the reduction of 4-nitrophenol (4-NP) and Cr. In the presence of ZnO-Ag NBs and AA, an effective reduction of 4-nitrophenol (4-NP) and Cr was achieved up to 93% and 90% in 17 and 26 min with respectively. The successful and efficient catalytic activity of NBs may be attributed to the size of NBs or the concentration of FA employed for synthesis.