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通过溶液吹纺法获得包封薄荷精油的聚乳酸纳米纤维作为潜在包装材料。

Obtaining poly (lactic acid) nanofibers encapsulated with peppermint essential oil as potential packaging via solution-blow-spinning.

机构信息

National Laboratory of Nanotechnology for Agriculture (LNNA), Embrapa Instrumentation, São Carlos 13560-970, São Paulo, Brazil.

Graduate Program in Biomaterials Engineering, Federal University of Lavras, Lavras 37200-000, Minas Gerais, Brazil.

出版信息

Int J Biol Macromol. 2023 Mar 1;230:123424. doi: 10.1016/j.ijbiomac.2023.123424. Epub 2023 Jan 25.


DOI:10.1016/j.ijbiomac.2023.123424
PMID:36708906
Abstract

The development of active packaging based on biodegradable material and incorporating active compounds, such as essential oil, is a new technique to ensure food safety without harming the environment. In this study, nanofiber mats of poly (lactic acid)/ polyethylene glycol (PLA/PEG) blend incorporated with peppermint essential oil (PO) at different ratios (5-20 % v/w) were produced by solution-blow-spinning (SBS) for potential packaging application. Electron microscopy showed a cylindrical and interlaced morphology for PLA/PEG/PO and a significant increase in the diameter (139-192 nm) of the nanofibers by increasing PO content. All nanofibers showed high thermal stability (278-345 °C) suitable for use in the food industry. Nuclear magnetic resonance (C NMR) spectrum confirmed PO in the nanofibers after SBS. ATR-FTIR spectral analysis supported the chemical composition of the nanofiber mats. PO addition led to obtaining hydrophobic nanofibers, enhancing the contact angle to 122° and decreasing water vapor permeability (60 % reduction compared to the PLA/PEG (3.0 g.mm.kPa.h.m). Although the PLA/PEG/20%PO nanofibers did not show halo formation in 24 h, they effectively extended the strawberries' shelf-life at 25 °C, evidencing PO release over time. It also reduced weight loss (2.5 % and 0.3 % weight loss after 5 days for PLA/PEG and PLA/PEG/20%PO, respectively) and increased firmness (8-12 N) for strawberries packed with the nanofiber mats. It is suggested that PLA/PEG films incorporating PO may be used as an active, environmentally friendly packaging material.

摘要

基于可生物降解材料并结合活性化合物(如精油)的活性包装的发展是确保食品安全而又不危害环境的新技术。在这项研究中,通过溶液纺丝(SBS)制备了不同比例(5-20%w/w)薄荷油(PO)的聚乳酸/聚乙二醇(PLA/PEG)共混物纳米纤维垫,用于潜在的包装应用。电子显微镜显示 PLA/PEG/PO 的形态为圆柱状和交织状,并且通过增加 PO 含量,纳米纤维的直径显著增加(139-192nm)。所有纳米纤维均表现出高的热稳定性(278-345°C),适用于食品工业。核磁共振(C NMR)谱证实了 SBS 后纳米纤维中的 PO。ATR-FTIR 光谱分析支持纳米纤维垫的化学成分。PO 的加入导致获得疏水性纳米纤维,接触角提高到 122°,水蒸气透过率降低(与 PLA/PEG(3.0g.mm.kPa.h.m)相比降低了 60%)。尽管 PLA/PEG/20%PO 纳米纤维在 24 小时内没有形成晕圈,但它们在 25°C 下有效地延长了草莓的货架期,证明了 PO 的释放随时间的推移而发生。它还减少了草莓的失重(PLA/PEG 和 PLA/PEG/20%PO 分别在 5 天后损失 2.5%和 0.3%的重量)并增加了草莓的硬度(8-12N)。建议将 PO 掺入 PLA/PEG 薄膜中可作为一种活性、环保的包装材料。

相似文献

[1]
Obtaining poly (lactic acid) nanofibers encapsulated with peppermint essential oil as potential packaging via solution-blow-spinning.

Int J Biol Macromol. 2023-3-1

[2]
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[3]
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[9]
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[10]
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引用本文的文献

[1]
Study of PVP and PLA Systems and Fibers Obtained by Solution Blow Spinning for Chlorhexidine Release.

Polymers (Basel). 2025-6-30

[2]
Microencapsulation to Harness the Antimicrobial Potential of Essential Oils and Their Applicability in Dairy Products: A Comprehensive Review of the Literature.

Foods. 2024-7-11

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