Deyab Mohamed A, Mohsen Q
Egyptian Petroleum Research Institute (EPRI), Nasr City, Cairo11727, Egypt.
Department of Chemistry, College of Sciences, Taif University, Taif11099, Saudi Arabia.
ACS Omega. 2023 Jan 9;8(3):3303-3309. doi: 10.1021/acsomega.2c06639. eCollection 2023 Jan 24.
The inhibitory capabilities of the sweet yellow capsicum extract (SYCE) toward the rusting of steel rebars in cement pore solution (CPS) were tested employing the electrochemical and mass loss methods. Gallic acid, caffeic acid, -coumaric acid, ferulic acid, luteolin, and cinnamic acid are the most important constituents in the SYCE extract. By adsorbing them on steel bars, the organic compounds in the CSA extract enable them with an effective mixed-type inhibition, suppressing both anodic and cathodic procedures. At 300 ppm, the highest performances were 95.3 and 97.5% utilizing mass loss and electrochemical approaches, respectively. The activation energy for the corrosion process is greatly increased by the addition of the SYCE extract, going from 13.2 kJ mol (blank solution) to 30.0 kJ mol (300 ppm SYCE extract). The physical adsorption actions of the SYCE extract are described by the Freundlich equilibrium constant's smallest value, which is 0.074 ppm. Many future investigators will be attracted by these discoveries to work relentlessly to uncover the anti-corrosion characteristics of novel plant extracts in the area of concrete additives.
采用电化学和质量损失法测试了甜黄辣椒提取物(SYCE)对水泥孔隙溶液(CPS)中钢筋锈蚀的抑制能力。没食子酸、咖啡酸、对香豆酸、阿魏酸、木犀草素和肉桂酸是SYCE提取物中最重要的成分。通过将它们吸附在钢筋上,CSA提取物中的有机化合物使其具有有效的混合型抑制作用,同时抑制阳极和阴极过程。在300 ppm时,采用质量损失法和电化学方法的最高抑制性能分别为95.3%和97.5%。添加SYCE提取物极大地提高了腐蚀过程的活化能,从13.2 kJ/mol(空白溶液)提高到30.0 kJ/mol(300 ppm SYCE提取物)。SYCE提取物的物理吸附作用由弗伦德利希平衡常数的最小值描述,该值为0.074 ppm。这些发现将吸引许多未来的研究人员不懈努力,以揭示新型植物提取物在混凝土添加剂领域的防腐特性。