Li Shumin, Jin Hui, Wang Yawen
Institute of Advanced Synthesis (IAS), Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, P.R. China.
Nanoscale. 2023 Feb 9;15(6):2488-2515. doi: 10.1039/d2nr06090f.
Benefiting from both one-dimensional (1D) morphology and alloy composition, metal alloy nanowires have been exploited as advanced electrocatalysts in various electrochemical processes. In this review, the synthesis approaches for metal alloy nanowires are classified into two categories: direct syntheses and syntheses based on preformed 1D nanostructures. Ligand systems that are of critical importance to the formation of alloy nanowires are summarized and reviewed, together with the strategies imposed to achieve the co-reduction of different metals. Meanwhile, different scenarios that form alloy nanowires from pre-synthesized 1D nanostructures are compared and contrasted. In addition, the characterization and electrocatalytic applications of metal alloy nanowires are briefly discussed.
得益于一维(1D)形态和合金成分,金属合金纳米线已被用作各种电化学过程中的先进电催化剂。在本综述中,金属合金纳米线的合成方法分为两类:直接合成和基于预制一维纳米结构的合成。总结并综述了对合金纳米线形成至关重要的配体系统,以及为实现不同金属的共还原所采用的策略。同时,比较并对比了由预合成的一维纳米结构形成合金纳米线的不同情况。此外,还简要讨论了金属合金纳米线的表征和电催化应用。