基于六方棱柱的 Mn(II)棒状金属-有机骨架的结构、SF6 气体吸附、磁性和电化学性质。

A hexagon based Mn(II) rod metal-organic framework - structure, SF gas sorption, magnetism and electrochemistry.

机构信息

Chemistry and Biochemistry, Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Gothenburg SE-41296, Sweden.

Department of Materials Science and Engineering, Ångström Laboratory, Uppsala University, Uppsala SE-751 03, Sweden.

出版信息

Chem Commun (Camb). 2023 Feb 16;59(15):2106-2109. doi: 10.1039/d2cc06916d.

DOI:10.1039/d2cc06916d

PMID:36723213

Abstract

A manganese(II) metal-organic framework based on the hexatopic hexakis(4-carboxyphenyl)benzene, cpb: [Mn(cpb)(dmf)], was solvothermally prepared showing a Langmuir area of 438 m g, rapid uptake OF sulfur hexafluoride (SF) as well as electrochemical and magnetic properties, while single crystal diffraction reveals an unusual rod-MOF topology.

摘要

基于六连接的六（4-羧基苯基）苯的锰(II)金属有机骨架，cpb：[Mn(cpb)(dmf)]，通过溶剂热法制备，具有 438 m²/g 的朗缪尔面积，对六氟化硫（SF6）具有快速的吸收能力，以及电化学和磁性性质，而单晶衍射则揭示了一种不寻常的棒状 MOF 拓扑结构。