Department of Chemistry, Graduate School of Advanced Science and Engineering, Hiroshima University, 1-3-1, Kagamiyama, Higashi-Hiroshima 739-8526, Japan.
International Institute for Sustainability with Knotted Chiral Meta Matter (SKCM2), Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan.
Chem Commun (Camb). 2023 Feb 23;59(17):2421-2424. doi: 10.1039/d2cc06502a.
A tetrakis(porphyrin) with branched side chains self-assembled to form supramolecular helical polymers both in solution and in the solid state. The helicity of the supramolecular polymers was determined by the chirality of solvent molecules, which permitted the polymer chains to be used in chiral sensing.
一种带有支链的四(卟啉)在溶液中和固态中自组装形成超分子螺旋聚合物。超分子聚合物的手性由溶剂分子的手性决定,这使得聚合物链可用于手性传感。