Shi Hua, He Xiaodong, Zhou Changjing, Wang Lili, Xiao Yuanxiang
Oil and Gas Technology Research Institute of Changqing Oilfield Company, PetroChina, Xi'an, 710018, Shaanxi, China.
School of Water and Environment, Chang'an University, No. 126 Yanta Road, Xi'an, 710054, Shaanxi, China.
Arch Environ Contam Toxicol. 2023 Feb;84(2):284-298. doi: 10.1007/s00244-023-00983-6. Epub 2023 Feb 3.
Hydraulic fracturing technologies have been frequently utilized in the oil and gas industry as exploration and development efforts have progressed, resulting in a significant increase in the extraction of natural gas and petroleum from low-permeability reservoirs. However, hydraulic fracturing requires a large amount of freshwater, and the process results in the production of large volumes of flowback water along with natural gas. In this study, three tight sandstone gas wells were fractured in the Sulige gasfield (China), and a total of 103 flowback fluid samples were collected. The hydrochemical characteristics, water quality and sources of hydrochemical components in the flowback fluid were discussed. The results show that the flowback fluid is characterized by high salinity (Total dissolved solids (TDS) up to 38,268 mg/L, Cl up to 24,000 mg/L), high concentrations of metal ions (e.g., Fe, Sr, Ba) and high chemical oxygen demand (COD). The flowback fluid is a complex mixture of fracturing fluid and formation water, and its composition is impacted by water-rock interactions that occur during hydraulic fracturing. The major contaminants include COD, Fe, Ba, Cl, Mn and pH, which constitute a high risk of environmental pollution. Meanwhile, chemical elements such as K, Ba and Sr are unusually enriched in the flowback fluid, which has an excellent potential for recycle of chemical elements. The Sulige gasfield's flowback fluid recovery methods and treatment scenarios were discussed, taking into consideration the pollution and resource characteristics of the flowback fluid. Options for dealing with the flowback fluid include deep well reinjection, reuse for making up fracturing fluid, recycling of chemical elements and diverse reuse of flowback water. This research offers guidance for managing the fracturing flowback fluid in unconventional oil and gas fields.
随着油气勘探开发工作的推进,水力压裂技术在油气行业中得到了频繁应用,使得从低渗透油藏中开采的天然气和石油量显著增加。然而,水力压裂需要大量淡水,并且该过程会产生大量伴生气的返排液。在本研究中,对中国苏里格气田的三口致密砂岩气井进行了压裂,并共采集了103个返排液样本。讨论了返排液的水化学特征、水质及水化学成分的来源。结果表明,返排液具有高盐度(总溶解固体(TDS)高达38268mg/L,Cl高达24000mg/L)、高浓度金属离子(如Fe、Sr、Ba)和高化学需氧量(COD)的特征。返排液是压裂液和地层水的复杂混合物,其成分受水力压裂过程中发生的水岩相互作用影响。主要污染物包括COD、Fe、Ba、Cl、Mn和pH值,构成了较高的环境污染风险。同时,K、Ba和Sr等化学元素在返排液中异常富集,具有良好的化学元素回收潜力。考虑到返排液的污染和资源特性,讨论了苏里格气田的返排液回收方法和处理方案。处理返排液的选项包括深井回注、用于补充压裂液的再利用、化学元素的回收以及返排水的多种再利用。本研究为非常规油气田压裂返排液的管理提供了指导。