Porous Polymer Supported Amino Functionalized Ionic Liquid for Effective CO Capture.

A decrease in CO emissions is urgently required in the present situation due to the fast growth of carbon dioxide (CO) in the atmosphere, which has caused a series of global climate issues. This study used an impregnation-evaporation method to immobilize an amino functionalized ionic liquid [COHmim][Lys] on a chromatographic column filler GDX-103 and create a novel supported ionic liquid. The results showed that the supported ionic liquid with 60 wt % ionic liquid content had the best adsorption performance at 40 °C, and the CO adsorption isotherm showed that the adsorption capacity at 0.1 MPa was 1.29 mmol CO/g sorbent, which was 6 times greater than the adsorption capacity of the pure carrier. The sample with 60% ionic liquid content has an adsorption capacity of 1.02 mmol CO/g sorbent under the condition of CO/N mixed gas with 10% CO content. This is 43 times greater than the adsorption capacity of the pure carrier, and its adsorption performance is stable after three adsorption and desorption cycles. Through the rich porous structure of GDX-103, the ionic liquid is effectively supported and dispersed, which expands the contact area between CO and ionic liquid and enhances the mass transfer of CO. At the same time, CO can be chemically bound to the groups on the anion of ionic liquid and be immobilized, so it has a high selective adsorption capacity of CO, which makes it a great alternative to traditional CO adsorbents.