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将铁和氧化锌纳米粒子原位锚定在稻壳纤维素上,用于高效废水修复。

In situ anchoring of iron and zinc oxides nanoparticles onto rice husk cellulose for efficient wastewater remediation.

机构信息

Chemistry Department, Faculty of Science, Tanta University, Tanta 31527, Egypt.

Chemistry Department, Faculty of Science, Tanta University, Tanta 31527, Egypt; Reference Lab of Holding Company for Water and Wastewater, Cairo 11631, Egypt.

出版信息

Int J Biol Macromol. 2023 Apr 1;233:123562. doi: 10.1016/j.ijbiomac.2023.123562. Epub 2023 Feb 6.

Abstract

The development of effective and economical technologies for the treatment of contaminated wastewater has been of great significance to researchers. Therefore, an equal molar ratio of iron and zinc oxides nanoparticles was hydrothermally immobilized on the cellulose fibers of rice husk. Using XRD, SEM, FTIR, EDX, TEM, VSM, BET, and TGA/DTG, the structure, and characteristics of Cel/α-FeO-ZnO, a ternary nanocomposite, were affirmed. The nanocomposite displayed a mesoporous structure with a substantial surface area. The efficiency of nanocomposite as a new adsorbent has been studied for the extraction of reactive black 5 (RB5), which is a diazo-anionic dye from simulated wastewater. The medium's pH was the dominant factor of RB5 adsorption, and the optimal removal effectiveness was acquired at pH 2. The adsorption values of RB5 correspond to second-order kinetics. They also matched Langmuir with a maximum capacity of 99.30 mg g. For real industrial wastewater, Cel/α-FeO-ZnO has successfully reduced a number of major pollutants, including ammonia (92.73 %), color (92.88 %), COD (91.53 %), BOD (84.97 %), TSS (96.27 %), TP (52.17 %) and TN (47.23 %). These results illustrate the effective application of the ternary nanocomposite in wastewater treatment.

摘要

开发高效、经济的受污染废水处理技术一直是研究人员关注的焦点。因此,采用水热法将等摩尔比的铁、锌氧化物纳米颗粒固定在稻壳纤维素纤维上。通过 XRD、SEM、FTIR、EDX、TEM、VSM、BET 和 TGA/DTG 对 Cel/α-FeO-ZnO 三元纳米复合材料的结构和特性进行了证实。该纳米复合材料具有介孔结构和较大的比表面积。研究了三元纳米复合材料作为一种新型吸附剂对模拟废水中的活性黑 5(RB5)(一种偶氮阴离子染料)的提取效率。吸附 RB5 的最佳 pH 值为 2,这表明介质 pH 是 RB5 吸附的主要影响因素。吸附值符合二级动力学模型,同时也符合 Langmuir 模型,最大容量为 99.30mg/g。对于实际工业废水,Cel/α-FeO-ZnO 成功去除了包括氨(92.73%)、颜色(92.88%)、COD(91.53%)、BOD(84.97%)、TSS(96.27%)、TP(52.17%)和 TN(47.23%)在内的多种主要污染物。这些结果表明,三元纳米复合材料在废水处理中具有有效的应用前景。

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