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通过修复剂介导将无定形共价有机聚合物转化为结晶共价有机骨架。

Converting an amorphous covalent organic polymer to a crystalline covalent organic framework mediated by a repairing agent.

作者信息

Han Xiang-Hao, Liang Rong-Ran, Zhou Zhi-Bei, Qi Qiao-Yan, Zhao Xin

机构信息

Key Laboratory of Synthetic and Self-Assembly Chemistry for Organic Functional Molecules, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.

出版信息

Chem Commun (Camb). 2023 Feb 23;59(17):2461-2464. doi: 10.1039/d2cc05800f.

DOI:10.1039/d2cc05800f
PMID:36752113
Abstract

We herein report a new approach to converting an amorphous covalent organic polymer to a crystalline heteropore covalent organic framework (COF), which is promoted by using an additive for structure repair. This provides a new method for the construction of COFs from cross-linked polymers.

摘要

我们在此报告一种将无定形共价有机聚合物转化为结晶性杂孔共价有机框架(COF)的新方法,该方法通过使用添加剂进行结构修复来促进。这为从交联聚合物构建COF提供了一种新方法。

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RSC Adv. 2023 Oct 16;13(43):30401-30419. doi: 10.1039/d3ra04855a. eCollection 2023 Oct 11.