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Review of computer simulations of isotope effects on biochemical reactions: From the Bigeleisen equation to Feynman's path integral.
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Integration of kinetic isotope effect analyses to elucidate ribonuclease mechanism.
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Mechanistic insights into RNA transphosphorylation from kinetic isotope effects and linear free energy relationships of model reactions.
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Roadmaps through free energy landscapes calculated using the multi-dimensional vFEP approach.
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Characterization of the reaction path and transition states for RNA transphosphorylation models from theory and experiment.
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