Althomali Raed H, Alamry Khalid A, Hussein Mahmoud A, Guedes R M
Department of Chemistry, Faculty of Science, King Abdulaziz University Jeddah 21589 Saudi Arabia
Chemistry Department, Faculty of Science, Assiut University Assiut 71516 Egypt.
RSC Adv. 2023 Jan 31;13(7):4303-4313. doi: 10.1039/d2ra07321h.
The multistep chemical modification of carboxymethylcellulose (CMC) in the presence of 4-aminophenazone (A-PH) and multiwall carbon nanotubes (MWCNTs) has been successfully conducted. The environmental performance of this material has been thoroughly investigated. Crystal violet (CV) and brilliant green (BG) were eliminated by utilising a new hybrid nanocomposite material (A-PH-CMC/MWCNTs) from a simulated textile wastewater solution. Using SEM, EDX, XRD and FTIR spectroscopy methods, the detailed characterisation of A-PH-CMC/MWCNT nanocomposites was investigated. The results indicated that the adsorption capacity was dependent on six factors (, contact duration, starting concentration, adsorbent mass, the effect of the solution pH, temperature and the effect of KNO). In addition, thermodynamic and regeneration studies have been reported. According to the theories of pseudo-second-order kinetics, the removal process involves chemical adsorption. The experimental results were best suited by the Langmuir model, in which maximum adsorption capacities of 20.83 and 22.42 mg g were predicted for the BG and CV dyes, respectively. The research is a preliminary case study demonstrating the excellent potential of A-PH-CMC/MWCNT nanocomposites as a material for CV and BG dye removal.
在4-氨基安替比林(A-PH)和多壁碳纳米管(MWCNTs)存在的情况下,成功进行了羧甲基纤维素(CMC)的多步化学改性。对该材料的环境性能进行了全面研究。利用一种新型杂化纳米复合材料(A-PH-CMC/MWCNTs)从模拟纺织废水溶液中去除了结晶紫(CV)和亮绿(BG)。采用扫描电子显微镜(SEM)、能量散射X射线光谱(EDX)、X射线衍射(XRD)和傅里叶变换红外光谱(FTIR)等方法,对A-PH-CMC/MWCNT纳米复合材料进行了详细表征。结果表明,吸附容量取决于六个因素(接触时间、初始浓度、吸附剂质量、溶液pH值的影响、温度以及硝酸钾的影响)。此外,还报道了热力学和再生研究。根据准二级动力学理论,去除过程涉及化学吸附。实验结果最符合朗缪尔模型,其中预测BG和CV染料的最大吸附容量分别为20.83和22.42 mg/g。该研究是一个初步的案例研究,证明了A-PH-CMC/MWCNT纳米复合材料作为去除CV和BG染料材料的巨大潜力。