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基于小分子主客体掺杂体系的刺激响应型有机磷光材料。

Stimulus-Responsive Organic Phosphorescence Materials Based on Small Molecular Host-Guest Doped Systems.

机构信息

College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, China.

School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 10081, China.

出版信息

J Phys Chem Lett. 2023 Feb 23;14(7):1794-1807. doi: 10.1021/acs.jpclett.2c03914. Epub 2023 Feb 10.

Abstract

Small molecular host-guest doped materials exhibit superiority toward high-efficiency room-temperature phosphorescence (RTP) materials due to their structural design diversity and ease of preparation. Dynamic RTP materials display excellent characteristics, such as good reversibility, quick response, and tunable luminescence ability, making them applicable to various cutting-edge technologies. Herein, we summarize the advances in host-guest doped dynamic RTP materials that respond to external and internal stimuli and present some insights into the molecular design strategies and underlying mechanisms. Subsequently, specific viewpoints are described regarding this promising field for the development of dynamic RTP materials. This Perspective is highly beneficial for future intelligent applications of dynamic RTP systems.

摘要

小分子主体-客体掺杂材料由于其结构设计多样性和制备简便性,在高效室温磷光(RTP)材料方面表现出优越性。动态 RTP 材料具有良好的可逆性、快速响应和可调发光能力等优异特性,使其适用于各种前沿技术。本文总结了对外界和内部刺激响应的主体-客体掺杂动态 RTP 材料的研究进展,并对分子设计策略和内在机制进行了深入探讨。随后,对动态 RTP 材料的发展提出了一些具体观点。本综述对动态 RTP 系统的未来智能应用具有重要意义。

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