铁(II)介导的席夫碱超分子结构及其自旋交叉性质。

Department of Industrial Chemistry, College of Applied Sciences, Addis Ababa Science and Technology University, Addis Ababa P.O. Box 16417, Ethiopia.

Nanotechnology Center of Excellence, Addis Ababa Science and Technology University, Addis Ababa P.O. Box 16417, Ethiopia.

Molecules. 2023 Jan 19;28(3):1012. doi: 10.3390/molecules28031012.

Supramolecular architectures, which are formed through the combination of inorganic metal cations and organic ligands by self-assembly, are one of the techniques in modern chemical science. This kind of multi-nuclear system in various dimensionalities can be implemented in various applications such as sensing, storage/cargo, display and molecular switching. Iron(II) mediated spin-crossover (SCO) supramolecular architectures with Schiff bases have attracted the attention of many investigators due to their structural novelty as well as their potential application possibilities. In this paper, we review a number of supramolecular SCO architectures of iron(II) with Schiff base ligands exhibiting varying geometrical possibilities. The structural and SCO behavior of these complexes are also discussed in detail.

超分子架构是通过自组装将无机金属阳离子和有机配体结合而形成的，是现代化学科学的技术之一。这种具有各种维度的多核系统可以在各种应用中实现，例如传感、存储/货物、显示和分子开关。由于其结构新颖性以及潜在的应用可能性，铁(II)介导的自旋交叉(SCO)超分子架构与希夫碱吸引了许多研究人员的关注。在本文中，我们回顾了具有希夫碱配体的铁(II)的一些超分子 SCO 架构，这些架构具有不同的几何可能性。还详细讨论了这些配合物的结构和 SCO 行为。