Sato Takahiro
Osaka Study Center, The Open University of Japan, 4-9-23, Onohara-Higashi, Osaka 562-0031, Japan.
Polymers (Basel). 2023 Jan 31;15(3):708. doi: 10.3390/polym15030708.
A lattice theory for block copolymer solutions near the boundary between the micellization and liquid-liquid phase separation regions proposes a new kinetic process of micellization where small concentrated-phase droplets are first formed and then transformed into micelles in the early stage of micellization. Moreover, the thermodynamically stable concentrated phase formed from metastable micelles by a unique ripening process in the late stage of phase separation, where the growing concentrated-phase droplet size is proportional to the square root of the time.
一种关于胶束化和液-液相分离区域边界附近嵌段共聚物溶液的晶格理论提出了一种新的胶束化动力学过程，即在胶束化早期首先形成小的浓相液滴，然后转变为胶束。此外，在相分离后期通过独特的熟化过程由亚稳态胶束形成热力学稳定的浓相，其中浓相液滴尺寸的增长与时间的平方根成正比。
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