Crystallization Kinetics of Modified Nanocellulose/Monomer Casting Nylon Composites.

Polyisocyanate and caprolactone were used to chemically functionalize nanocellulose (CNF). Composites of CNF, caprolactone-modified nanocellulose (CNF-CL) and polyisocyanate-modified nanocellulose (CNF-JQ)/MC nylon were fabricated by anionic ring-opening polymerization. The effects of the crystal structure, crystal morphology and crystallization process of MC nylon composites have been characterized by wide-angle X-ray diffraction (WAXD), polarized optical microscopy(POM) and differential scanning calorimetry (DSC). Isothermal crystallization kinetics were analyzed using the Avrami equation, and the crystallization rate, half-time, and Avrami exponent were calculated. The results show that the nucleation effects of CNF-JQ/MC nylon composites is increased with the CNF-JQ increase, and it is best compared with MC nylon, CNF/MC nylon and CNF-CL/MC nylon composites, so CNF-JQ can play the role of effective nucleating agent in MC nylon. We also discussed the non-isothermal crystallization of the composites. Analysis of the Jeziorny and Mo model demonstrates that the Zc values of CNF, CNF-CL, CNF-JQ/MC nylon composites increase, and the F(T) values decrease in order. This indicates that CNF-JQ can better promote the crystallization rate of non-isothermal crystallization of MC nylon. The results of this work demonstrate that CNF-JQ can be an effective nucleation agent and increase the crystallization rate of MC nylon compared with CNF-CL. The activation energy of the composites was studied using the kissing method, and the results showed that CNF-CL decreased the activation energy of MC nylon, and CNF and CNF-JQ increased the activation energy of MC nylon.