Epure Elena-Luiza, Cojocaru Florina Daniela, Aradoaei Mihaela, Ciobanu Romeo Cristian, Dodi Gianina
Faculty of Chemical Engineering and Environmental Protection, Gheorghe Asachi Technical University, Mangeron Bd., 700454 Iasi, Romania.
Advanced Research and Development Center for Experimental Medicine, Grigore T. Popa University of Medicine and Pharmacy of Iasi, 9-13 M. Kogalniceanu Street, 700454 Iasi, Romania.
Polymers (Basel). 2023 Feb 3;15(3):776. doi: 10.3390/polym15030776.
With a significant number of features (namely being multipurpose, inexpensive and durable), thermoplastic polymers, most often named plastics, are part of our daily routine, with an increasing production over the last decade. Among them, polyethylene terephthalate (PET), high-density polyethylene (HDPE) and polypropylene (PP) are distinguished as the five most commonly used plastics in various fields, mainly in the packaging industry. Even if it is difficult to imagine the world without plastics, the boosted plastic assembly comes with huge plastic waste, creating a number of challenges, as the most important threat for our environment, but also opportunities for recycling. Currently, a special attention is dedicated on how to improve the current recycling methods or to find new ones, since the quality of recycled plastics and potential chemical or biological contaminations are two problematic aspects. Understanding the properties of each thermoplastic polymer and the interaction with possible contaminants may be the key for an efficient recycling process. The aim of this paper was to evaluate the surface behaviour of different composite supports based on recycled PET before and after interaction with collagen (used as a biological contaminant). The surface contamination bias of PET supports was studied through different techniques: scanning electron microscopy (SEM), water uptake through swelling studies, contact angle measurements and attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR).
由于具有大量特性(即多功能、价格低廉且耐用),热塑性聚合物(通常称为塑料)已成为我们日常生活的一部分,并且在过去十年中产量不断增加。其中,聚对苯二甲酸乙二酯(PET)、高密度聚乙烯(HDPE)和聚丙烯(PP)是在各个领域(主要是包装行业)中最常用的五种塑料。尽管很难想象没有塑料的世界,但塑料产量的增加带来了大量塑料垃圾,这带来了许多挑战,既是对我们环境的最大威胁,也带来了回收利用的机会。目前,人们特别关注如何改进当前的回收方法或寻找新的回收方法,因为回收塑料的质量以及潜在的化学或生物污染是两个存在问题的方面。了解每种热塑性聚合物的特性以及与可能的污染物之间的相互作用可能是实现高效回收过程的关键。本文的目的是评估基于回收PET的不同复合载体在与胶原蛋白(用作生物污染物)相互作用前后的表面行为。通过不同技术研究了PET载体的表面污染偏差:扫描电子显微镜(SEM)、通过溶胀研究测定吸水率、接触角测量以及衰减全反射傅里叶变换红外光谱(ATR-FTIR)。