Zhai Rui, Zhang Lihui, Gu Mengyue, Zhao Xuewen, Zhang Bo, Cheng Yonghong, Zhang Jinying
State Key Laboratory of Electrical Insulation and Power Equipment, Center of Nanomaterials for Renewable Energy (CNRE), School of Electrical Engineering, Xi'an Jiaotong University, Xi'an, 710049, P. R. China.
Small. 2023 May;19(19):e2207840. doi: 10.1002/smll.202207840. Epub 2023 Feb 12.
Effective photocatalytic carbon dioxide (CO ) reduction into high-value-added chemicals is promising to mitigate current energy crisis and global warming issues. Finding effective photocatalysts is crucial for photocatalytic CO reduction. Currently, metal-based semiconductors for photocatalytic CO reduction have been well reviewed, while review of nonmetal-based semiconductors is almost limited to carbon nitrides. Phosphorus is a promising nonmetal photocatalysts with various allotropes and tunable band gaps, which has been demonstrated to be promising non-metallic photocatalysts. However, no systematic review about phosphorus structures for photocatalytic CO reduction reactions has been reported. Herein, the progresses of phosphorus structures as photocatalysts for CO reduction are reviewed. The fundamentals of photocatalytic CO reduction, corresponding properties of phosphorus allotropes, photocatalysts with phosphorus doping or phosphorus-containing ligands, research progress of phosphorus allotropes as photocatalysts for CO reduction have been reviewed in this paper. The future research and perspective of phosphorus structures for photocatalytic CO reduction are also presented.
将二氧化碳（CO₂）有效地光催化还原为高附加值化学品，有望缓解当前的能源危机和全球变暖问题。寻找有效的光催化剂对于光催化CO₂还原至关重要。目前，用于光催化CO₂还原的金属基半导体已有详尽综述，而非金属基半导体的综述几乎仅限于碳氮化物。磷是一种有前景的非金属光催化剂，具有多种同素异形体和可调节的带隙，已被证明是有前景的非金属光催化剂。然而，尚未有关于用于光催化CO₂还原反应的磷结构的系统综述报道。在此，对作为光催化剂用于CO₂还原的磷结构进展进行综述。本文综述了光催化CO₂还原的基本原理、磷同素异形体的相应性质、含磷掺杂或含磷配体的光催化剂、磷同素异形体作为光催化剂用于CO₂还原的研究进展。还介绍了用于光催化CO₂还原的磷结构的未来研究和展望。
