Kariaka Nataliia S, Dyakonenko Viktoriya V, Shishkina Svitlana V, Sliva Tatiana Yu, Amirkhanov Vladimir M
Department of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska, str. 64, 01601 Kyiv, Ukraine.
SSI "Institute for Single Crystals", National Academy of Sciences of Ukraine, Nauky ave. 60, 61001 Kharkiv, Ukraine.
Acta Crystallogr E Crystallogr Commun. 2023 Jan 6;79(Pt 2):70-73. doi: 10.1107/S2056989022012166. eCollection 2023 Jan 1.
The caesium salt of dimethyl--benzoyl-amido-phosphate, namely, aqua-[di-meth-yl (-benzoyl-amido-κ)phospho-nato-κ]caesium, [Cs(CHNOP)(HO)] or Cs·HO, is reported. The compound crystallizes in the monoclinic crystal system in the 2/ space group and forms a mono-periodic polymeric structure due to the bridging function of the dimethyl--benzoyl-amido-phosphate anions towards the caesium cations.
报道了二甲基 - 苯甲酰氨基磷酸铯盐,即水合 - [二甲基(苯甲酰氨基 - κ)磷酸根合 - κ]铯,[Cs(CHNOP)(HO)] 或 Cs·HO。该化合物在单斜晶体系统中以2/空间群结晶,由于二甲基 - 苯甲酰氨基磷酸根阴离子对铯阳离子的桥连作用,形成了单周期聚合物结构。