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具有增强固态荧光的氮掺杂碳点/水滑石纳米复合材料用于识别潜在指纹。

Nanocomposites of nitrogen-doped carbon dots/hydrotalcite with enhanced solid-state fluorescence for the recognition of latent fingerprints.

作者信息

Li Da-Wu, Zhang Xing-Fu, Zhang Xiao-Tong, Lv Xiao-Sen, You Nan

机构信息

College of Forensic Science, Criminal Investigation Police University of China, Shenyang, Liaoning, 110035, China.

Key Laboratory of Impression Evidence Examination and Identification Technology, Ministry of Public Security, Shenyang, Liaoning, 110035, China.

出版信息

Anal Methods. 2023 Mar 9;15(10):1297-1305. doi: 10.1039/d2ay01952c.


DOI:10.1039/d2ay01952c
PMID:36804549
Abstract

In this work, a green emissive nanocomposite was synthesized by embedding nitrogen-doped carbon dots into hydrotalcite (N-CD/hydrotalcite) a hydrothermal process for the recognition of latent fingerprints (LFPs). Good dispersion of the nano-sized N-CD on the surface of hydrotalcite overcomes the fluorescence quenching of N-CD in the solid state and can enhance solid-state fluorescence. N-CD/hydrotalcite emits stable strong green fluorescence even at different excitation wavelengths and exhibits good selectivity and sensitivity for the visualization of LFPs on various substrates such as glass slides, tiles, leather, aluminum foil, printing paper, colored surfaces of plastic packing, copper foil, planks, leaves, currencies, and bar codes. The high-level details of the ridge patterns of both fresh and aged LFPs can be clearly identified with good clarity and high contrast without background interferences under the excitation of a 450 nm light source. There is no significant difference in the LFP image visualized by N-CD/hydrotalcite and commercial fluorescent powders, indicating that the effectiveness of N-CD/hydrotalcite for the visualization of LFPs is equivalent to that of commercial fluorescent powders. These observations illustrate that N-CD/hydrotalcite has great potential in the recognition of LFPs.

摘要

在这项工作中,通过水热法将氮掺杂碳点嵌入水滑石中合成了一种绿色发光纳米复合材料(N-CD/水滑石),用于识别潜在指纹(LFP)。纳米尺寸的N-CD在水滑石表面良好分散,克服了N-CD在固态下的荧光猝灭,增强了固态荧光。即使在不同激发波长下,N-CD/水滑石也能发射稳定的强绿色荧光,并且对在各种基材(如载玻片、瓷砖、皮革、铝箔、印刷纸、塑料包装彩色表面、铜箔、木板、树叶、货币和条形码)上可视化LFP表现出良好的选择性和灵敏度。在450nm光源激发下,新鲜和陈旧LFP的脊纹图案的高级细节都能清晰识别,清晰度高、对比度好,且无背景干扰。N-CD/水滑石可视化的LFP图像与商业荧光粉无显著差异,表明N-CD/水滑石用于可视化LFP的效果与商业荧光粉相当。这些观察结果表明,N-CD/水滑石在识别LFP方面具有巨大潜力。

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