Kawaguchi Kaede, Ito Masato, Kubo Yuji
Department of Applied Chemistry for Environment, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachioji, Tokyo, 192-0397, Japan.
Chem Commun (Camb). 2023 Mar 9;59(21):3130-3133. doi: 10.1039/d2cc07049a.
Boronate assemblies, derived from benzene-1,4-diboronic acid, showed room-temperature phosphorescence (RTP) in both the solid-state and dispersions, being quite sensitive to the preparation conditions. Our chemometrics-assisted quantitative structure-property relationship (QSPR) analysis between the nanostructure and RTP behavior of boronate assemblies led us not only to understand their RTP mechanism but also to predict the RTP properties of unknown assemblies from the PXRD patterns.
源自苯-1,4-二硼酸的硼酸酯组装体在固态和分散体中均表现出室温磷光（RTP），且对制备条件相当敏感。我们通过化学计量学辅助的硼酸酯组装体纳米结构与RTP行为之间的定量结构-性质关系（QSPR）分析，不仅使我们了解了它们的RTP机制，还能根据粉末X射线衍射（PXRD）图谱预测未知组装体的RTP性质。
