Novel development of zinc oxide-coated carbon nanoparticles from pineapple leaves using sol gel method for optimal adsorption of Cu and reuse in latent fingerprint application.

This study underlines a latest approach of preparing nitrogen carbon nanoparticles fused on zinc oxide nanoparticle nanocomposite (N-CNPs/ZnONP nanocomposite) for the uptake of copper ions (Cu) from wastewater using a sol gel method. The metal loaded adsorbent was then applied in the latent fingerprint application. N-CNPs/ZnONP nanocomposite proved to be a good sorbent for the optimal adsorption of Cu at pH 8 and 1.0 g/L dosage. Langmuir isotherm best fitted the process with the maximum adsorption capacity of 285.71 mg/g that was superior to most values reported in other studies for the removal of Cu. At 25 °C, the adsorption was spontaneous and endothermic. Furthermore, Cu-N-CNPs/ZnONP nanocomposite revealed to be sensitive and selective for latent fingerprint (LFP) identification on a variety of porous surfaces. As a result, it is an excellent identifying chemical for latent fingerprint recognition in forensic science.