Chang Jinming, Dou Li, Ye Yu, Zhang Kankan
National Key Laboratory of Green Pesticide, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Center for R&D of Fine Chemicals, Guizhou University, Guiyang 550025, China.
Foods. 2023 Feb 19;12(4):892. doi: 10.3390/foods12040892.
Tomato and cucumber are two vital edible vegetables that usually appear in people's daily diet. Penthiopyrad is a new type of amide chiral fungicide, which is often used for disease control of vegetables (including tomato and cucumber) due to its wide bactericidal spectrum, low toxicity, good penetration, and strong internal absorption. Extensive application of penthiopyrad may have caused potential pollution in the ecosystem. Different processing methods can remove pesticide residues from vegetables and protect human health. In this study, the penthiopyrad removal efficiency of soaking and peeling from tomatoes and cucumbers was evaluated under different conditions. Among different soaking methods, heated water soaking and water soaking with additives (NaCl, acetic acid, and surfactant) presented a more effective reduction ability than other treatments. Due to the specific physicochemical properties of tomatoes and cucumbers, the ultrasound enhances the removal rate of soaking for tomato samples and inhibits it for cucumber samples. Peeling can remove approximately 90% of penthiopyrad from contaminated tomato and cucumber samples. Enantioselectivity was found only during tomato sauce storage, which may be related to the complex microbial community. Health risk assessment data suggests that tomatoes and cucumbers are safer for consumers after soaking and peeling. The results may provide consumers with some useful information to choose better household processing methods to remove penthiopyrad residues from tomatoes, cucumbers, and other edible vegetables.
番茄和黄瓜是两种重要的可食用蔬菜,它们经常出现在人们的日常饮食中。戊唑菌胺是一种新型的酰胺类手性杀菌剂,由于其杀菌谱广、毒性低、渗透性好和内吸性强,常用于蔬菜(包括番茄和黄瓜)的病害防治。戊唑菌胺的广泛应用可能已对生态系统造成潜在污染。不同的加工方法可以去除蔬菜中的农药残留,保护人类健康。在本研究中,评估了在不同条件下番茄和黄瓜浸泡及去皮对戊唑菌胺的去除效率。在不同的浸泡方法中,热水浸泡和添加物(氯化钠、乙酸和表面活性剂)浸泡比其他处理表现出更有效的降低能力。由于番茄和黄瓜的特定理化性质,超声处理提高了番茄样品浸泡的去除率,却抑制了黄瓜样品浸泡的去除率。去皮可以从受污染的番茄和黄瓜样品中去除约90%的戊唑菌胺。仅在番茄酱储存期间发现了对映体选择性,这可能与复杂的微生物群落有关。健康风险评估数据表明,浸泡和去皮后的番茄和黄瓜对消费者更安全。研究结果可为消费者提供一些有用信息,以便他们选择更好的家庭加工方法来去除番茄、黄瓜及其他可食用蔬菜中的戊唑菌胺残留。