Cao Furong, Guo Huizhen, Guo Nanpan, Kong Shuting, Liang Jinrui
School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China.
State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, China.
Materials (Basel). 2023 Feb 16;16(4):1639. doi: 10.3390/ma16041639.
To explore room-temperature strengthening and high-temperature ductility, a lightweight novel Mg-1.85Gd-0.64Al-0.62Zn alloy was fabricated by innovative multidirectional forging and a hot-rolling technique. Microstructures and mechanical properties were studied at room and elevated temperatures with an optical microscope, an X-ray diffractometer, and a tensile tester. An ultimate tensile strength of 260 MPa, yield strength of 171 MPa, and elongation of 20.4% were demonstrated at room temperature. The room-temperature strengthening mechanisms were identified by strengthening the model estimation. A type C Portevin-Le Chatelier effect was discovered and elucidated in this alloy. X-ray diffraction analysis revealed that the phase composition is α-Mg solid solution and (Mg, Al)Gd, AlZn, and AlGd intermetallic compounds. Examination of the microstructure at elevated temperatures revealed that dynamic recrystallization and dynamic grain growth occur. In particular, it was discovered that bimodal microstructures or incomplete dynamic recrystallization microstructures exist in high-temperature deformation. A maximum quasi-superplasticity of 228.4% was demonstrated in this alloy at 673 K and 5.0 × 10 s. Flow stress curves showed that the present alloy exhibits Sotoudeh-Bate curves or a long intermediate strain-hardening stage followed by a strain-softening stage. A modified Zerilli-Armstrong constitutive equation incorporating the number of dislocations was established. The power-law constitutive equation was established to identify the deformation mechanism. Both constitutive models had good predictability. At 673 K and 5.0 × 10 s, the stress exponent was 4, and the average deformation activation energy was 104.42 kJ/mol. The number of dislocations inside a grain was 146. This characteristic evidence confirmed that dislocation motion controlled by pipe diffusion dominates the rate-controlling process under this condition.
为了探索室温强化和高温延展性,采用创新的多向锻造和热轧技术制备了一种轻质新型Mg-1.85Gd-0.64Al-0.62Zn合金。利用光学显微镜、X射线衍射仪和拉伸试验机对室温和高温下的微观结构和力学性能进行了研究。室温下的抗拉强度为260MPa,屈服强度为171MPa,伸长率为20.4%。通过强化模型估计确定了室温强化机制。在该合金中发现并阐明了C型Portevin-Le Chatelier效应。X射线衍射分析表明,相组成是α-Mg固溶体以及(Mg,Al)Gd、AlZn和AlGd金属间化合物。对高温下微观结构的研究表明,发生了动态再结晶和动态晶粒长大。特别是,发现在高温变形中存在双峰微观结构或不完全动态再结晶微观结构。该合金在673K和5.0×10s时表现出最大准超塑性为228.4%。流变应力曲线表明,该合金呈现Sotoudeh-Bate曲线或长的中间应变硬化阶段,随后是应变软化阶段。建立了一个包含位错数量的修正Zerilli-Armstrong本构方程。建立幂律本构方程以确定变形机制。两种本构模型都具有良好的预测性。在673K和5.0×10s时,应力指数为4,平均变形激活能为104.42kJ/mol。晶粒内的位错数量为146。这一特征证据证实,在这种条件下,由管道扩散控制的位错运动主导了速率控制过程。