Kharlamova Marianna V, Kramberger Christian
Centre for Advanced Materials Application (CEMEA), Slovak Academy of Sciences, Dúbravská cesta 5807/9, 845 11 Bratislava, Slovakia.
Faculty of Physics, University of Vienna, Boltzmanngasse 5, 1090 Vienna, Austria.
Nanomaterials (Basel). 2023 Feb 19;13(4):774. doi: 10.3390/nano13040774.
In this paper, the growth mechanism, structure, growth processes, growth kinetics, and optical, vibronic and electronic properties of metallocene-filled single-walled carbon nanotubes (SWCNTs) are considered. A description of the procedures used to fill the nanotubes is provided. An investigation of doping effects on metallicity-mixed SWCNTs filled with metallocenes by Raman spectroscopy, near edge X-ray absorption fine structure spectroscopy, photoemission spectroscopy, and optical absorption spectroscopy is described. The studies of doping effects on metallicity-sorted SWCNTs filled with metallocenes are discussed. Doping effects in metallicity-mixed and sorted SWCNTs upon the chemical transformation of encapsulated molecules are analyzed. A discussion of the modification of the electronic properties of filled SWCNTs is presented. Applications of metallocene-filled SWCNTs in electrochemistry, thermoelectric power generation, chemical sensors, and magnetic recording are discussed.
本文考虑了茂金属填充的单壁碳纳米管（SWCNT）的生长机制、结构、生长过程、生长动力学以及光学、振动和电子性质。提供了用于填充纳米管的程序描述。描述了通过拉曼光谱、近边X射线吸收精细结构光谱、光电子能谱和光吸收光谱对掺杂对填充有茂金属的金属性混合SWCNT的影响的研究。讨论了对填充有茂金属的金属性分类SWCNT的掺杂效应研究。分析了金属性混合和分类的SWCNT在封装分子化学转化时的掺杂效应。给出了对填充SWCNT电子性质改性的讨论。讨论了茂金属填充的SWCNT在电化学、热电发电、化学传感器和磁记录中的应用。
