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污泥与高钠煤的共气化协同特性

Co-Gasification Synergistic Characteristics of Sewage Sludge and High-Sodium Coal.

作者信息

Zhang Zhiyuan, Zhang Lilin, Liu Yin, Lv Mingxu, You Peibo, Wang Xutao, Zhou Hengtao, Wang Jing

机构信息

School of Energy and Architectural Environment Engineering, Henan University of Urban Construction, Pingdingshan467036, China.

School of Energy and Environment, Zhongyuan University of Technology, Zhengzhou450007, China.

出版信息

ACS Omega. 2023 Feb 9;8(7):6571-6583. doi: 10.1021/acsomega.2c06962. eCollection 2023 Feb 21.

Abstract

A comprehensive study was conducted to assess the co-gasification characteristics of sewage sludge and high-sodium coal. As the gasification temperature increased, the CO concentration was decreased, and the concentrations of CO and H were increased, while the change of CH concentration was not obvious. As the coal blending ratio increased, the H and CO concentrations initially increased and then decreased, while the CO concentration initially decreased and then increased. The mixture of sewage sludge and high-sodium coal shows the synergistic effect of co-gasification, and the synergistic effect was to promote the gasification reaction positively. The average activation energies of co-gasification reactions were calculated by the OFW method, and the average activation energy initially decreases and then increases as the coal blending ratio increases. Both fluidized-bed gasification and thermogravimetric analyzer gasification show that the optimum coal blending ratio is 0.6. Overall, these results provide a theoretical basis for the industrial application of sewage sludge and high-sodium coal co-gasification.

摘要

开展了一项综合研究以评估污水污泥与高钠煤的共气化特性。随着气化温度升高,CO浓度降低,CO₂和H₂浓度升高,而CH₄浓度变化不明显。随着配煤比增加,H₂和CO浓度先升高后降低,而CO₂浓度先降低后升高。污水污泥与高钠煤的混合物表现出共气化的协同效应,且该协同效应正向促进气化反应。采用OFW法计算了共气化反应的平均活化能,平均活化能随配煤比增加先降低后升高。流化床气化和热重分析仪气化均表明最佳配煤比为0.6。总体而言,这些结果为污水污泥与高钠煤共气化的工业应用提供了理论依据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8b56/9947966/29fd1be6212e/ao2c06962_0002.jpg

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