Impact of Different Ratios of Lignin Waste and Liquid Glass on the Performance Characteristics of Biopolyurethane Foams.

In the current study, biopolyurethane foam was modified with 2.5-10 wt.% lignin waste (LigW) and liquid glass (LG)-modified LigW particles at different LigW/LG ratios-1:1 and 1:2-and their impact on performance characteristics-i.e., rheology, foaming times, apparent density, thermal conductivity before and after aging, dimensional stability at ambient and elevated conditions, compressive and tensile strengths, short-term water absorption by partial immersion, and water vapor permeability-was determined and evaluated. Structural analysis was implemented and structural parameters were taken into consideration as well. During the study, it was determined that 2.5-10 wt.% particles at the LigW/LG ratio of 1:2 showed a superior impact on the physical and mechanical properties of bioPUR foams. The apparent density only insignificantly increased and was in a density range suitable for commercially available polyurethanes. For particles at 10 wt.% and LigW/LG ratio of 1:1, the thermal conductivity value improved by 3.2%, the compressive strength increased by 153%, while the tensile strength improved by 23.5%, indicating sufficient interfacial adhesion between the filler and polymer matrix. Moreover, the short-term water absorption by partial immersion remained almost unchanged, while the water vapour diffusion resistance factor improved from 43 to 48. Additionally, the incorporation of LigW/LG 1:1 and LigW/LG 1:2 particles made it possible to obtain dimensionally and structurally stable closed-cell bioPUR foams for possible application as thermal insulation in building envelopes.