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普通蓟叶提取物在盐酸介质中作为一种环保型缓蚀剂用于低碳钢。

Falcaria vulgaris leaves extract as an eco-friendly corrosion inhibitor for mild steel in hydrochloric acid media.

机构信息

Chemical and Petroleum Engineering Department, Sharif University of Technology, Tehran, Iran.

Surface Coating and Corrosion Department, Institute for Color Science and Technology, Tehran, Iran.

出版信息

Sci Rep. 2023 Mar 6;13(1):3737. doi: 10.1038/s41598-023-30571-6.

Abstract

Undoubtedly, metal corrosion is one of the most challenging problems faced by industries. Introducing corrosion inhibitors is a reasonable approach to protecting the metal surface. Due to environmental concerns and the toxicity of industrial organic corrosion inhibitors, researchers are continually exploring acceptable replacements. The current study focused on the application of Falcaria Vulgaris (FV) leaves extract to mitigate mild steel (MS) corrosion in a 1 M HCl environment. The polarization findings demonstrated that the corrosion current density decreased from 264.0 µA/cm (for the sample submerged in the blank solution) to 20.4 µA/cm when the optimal concentration of 800 ppm of FV leaves extract was added to the acid solution. Electrochemical impedance spectroscopy (EIS) analysis revealed an inhibition efficiency of 91.3% at this concentration after 6 h of immersion. It was determined by analyzing several adsorption isotherms that this corrosion inhibitor obeys the Frumkin isotherm. AFM, FE-SEM, and GIXRD surface analyses also supported the findings that adding FV leaves extract can reduce metal damage by adsorption on the metal surface.

摘要

毫无疑问,金属腐蚀是工业界面临的最具挑战性的问题之一。引入腐蚀抑制剂是保护金属表面的合理方法。由于对环境的关注和工业有机腐蚀抑制剂的毒性,研究人员一直在探索可接受的替代品。本研究专注于利用普通刺柏(FV)叶提取物来减轻在 1M HCl 环境中对低碳钢(MS)的腐蚀。极化结果表明,当将 800ppm 的最佳浓度的 FV 叶提取物添加到酸溶液中时,腐蚀电流密度从在空白溶液中浸泡的样品的 264.0 µA/cm 降低到 20.4 µA/cm。电化学阻抗谱(EIS)分析表明,在 6 小时浸泡后,该浓度下的抑制效率为 91.3%。通过分析几种吸附等温线,确定该腐蚀抑制剂遵循 Frumkin 等温线。AFM、FE-SEM 和 GIXRD 表面分析也支持这样的发现,即添加 FV 叶提取物可以通过在金属表面吸附来减少金属损伤。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/534c/9988855/e0e9160d22c0/41598_2023_30571_Fig1_HTML.jpg

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