Macao Institute of Materials Science and Engineering (MIMSE), Macao University of Science and Technology, Taipa 999078, Macao, China.
Zhuhai MUST Science and Technology Research Institute, Zhuhai 519099, China.
Nanoscale. 2023 Mar 23;15(12):5720-5725. doi: 10.1039/d2nr06998a.
Perovskite nanocrystals have attracted much attention due to their unique optical and electronic properties. Much progress has also been made in the development of light-emitting diodes based on perovskite nanocrystals in the past years. However, compared with the widely reported opaque perovskite nanocrystal light-emitting diodes, semitransparent perovskite nanocrystal light-emitting diodes are rarely studied, which affects the potential application of perovskite nanocrystals in the translucent display field in the future. Here, poly[(9,9-bis(3'-(,-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)] (PFN), a conjugated polymer, was used as an electron transport layer to fabricate the inverted opaque and semitransparent perovskite light-emitting diodes. The maximum external quantum efficiency and luminance were improved from 0.13% and 1041 cd m to 2.07% and 12 540 cd m, respectively, through device optimization in opaque light-emitting diodes. The corresponding semitransparent device also demonstrated high transmittance (average 61% from 380 to 780 nm) and high brightness of 1619 and 1643 cd m for the bottom and top sides, respectively.
钙钛矿纳米晶因其独特的光学和电子特性而受到广泛关注。在过去的几年中,基于钙钛矿纳米晶的发光二极管的发展也取得了很大的进展。然而,与广泛报道的不透明钙钛矿纳米晶发光二极管相比,半透明钙钛矿纳米晶发光二极管的研究很少,这影响了钙钛矿纳米晶在未来半透明显示领域的潜在应用。在这里,聚[[9,9-双(3'-(,-二甲基氨基)丙基)-2,7-芴]--alt-2,7-(9,9-二辛基芴)] (PFN),一种共轭聚合物,被用作电子传输层来制备倒置不透明和半透明的钙钛矿发光二极管。通过对不透明发光二极管进行器件优化,最大外量子效率和亮度分别从 0.13%和 1041 cd m 提高到 2.07%和 12540 cd m。相应的半透明器件也表现出高透过率(从 380 到 780nm 的平均透过率为 61%)和高亮度,底部和顶部的亮度分别为 1619 和 1643 cd m。