Department of Chemistry, University of California Berkeley, Berkeley, CA, 94720, USA.
Kavli Energy Nanoscience Institute at UC Berkeley, Berkeley, CA, 94720, USA.
Adv Mater. 2023 Apr;35(17):e2300018. doi: 10.1002/adma.202300018. Epub 2023 Mar 9.
Atmospheric water harvesting using reticular materials is an innovation that has the potential to change the world. Using covalent organic frameworks (COFs) for capturing water holds great promise because COFs are metal-free, stable under working conditions, and their structure can be intentionally designed to meet the requirements for this application. To promote the chemistry and use of COFs for atmospheric water harvesting, important features for synthesizing suitable water-harvesting COFs are discussed. The achievements of using COFs as water harvesters are then highlighted, showing how the water harvesting properties are related to the structural design. Finally, perspectives and research directions for further studies in COF chemistry are provided.
利用网状材料进行大气水收集是一项具有改变世界潜力的创新。使用共价有机框架(COFs)来捕获水具有很大的前景,因为 COFs 不含金属,在工作条件下稳定,并且可以有意设计其结构以满足此应用的要求。为了促进 COFs 在大气水收集方面的化学应用,讨论了合成合适的水收集 COFs 的重要特征。然后强调了将 COFs 用作水收集器的成就,展示了水收集性能如何与结构设计相关。最后,提供了对 COF 化学进一步研究的观点和研究方向。