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使用化学镀粉和共沉淀粉对WC-10(Ni,Ni/Co)硬质合金的致密化、微观结构及性能的对比研究

Comparative Study on the Densification, Microstructure and Properties of WC-10(Ni, Ni/Co) Cemented Carbides Using Electroless Plated and Coprecipitated Powders.

作者信息

Jiang Haoli, Tong Jing, Zhan Zhaoqing, Yao Zhanhu, Yu Songbai, Min Fanlu, Wang Congxu, Noudem Jacques Guillaume, Zhang Jianfeng

机构信息

College of Mechanics and Materials, Hohai University, Nanjing 211100, China.

CCCC Tunnel Engineering Company Limited, Beijing 100102, China.

出版信息

Materials (Basel). 2023 Feb 28;16(5):1977. doi: 10.3390/ma16051977.

Abstract

More and more attention is being paid to the influence of powder mixing on the mechanical properties and corrosion resistance of WC-based cemented carbides. In this study, WC was mixed with Ni and Ni/Co, respectively, by chemical plating and co-precipitated-hydrogen reduction, which are labelled as WC-Ni, WC-Ni/Co, WC-Ni and WC-Ni/Co, respectively. After being densified in a vacuum, the density and grain size of CP were denser and finer than those of EP were. Simultaneously, the better mechanical properties of flexural strength (1110 MPa) and impact toughness (33 kJ/m) were obtained by WC-Ni/Co due to the uniform distribution of WC and binding phase and solid solution enhancement of the Ni-Co alloy. In addition, the lowest self-corrosion current density of 8.17 × 10 A·cm, a self-corrosion potential of -0.25 V and the biggest corrosion resistance of 1.26 × 10 Ω in 3.5 wt % NaCl solution were obtained by WC-Ni because of the presence of the Ni-Co-P alloy.

摘要

粉末混合对WC基金属陶瓷的力学性能和耐蚀性的影响越来越受到关注。在本研究中,WC分别通过化学镀和共沉淀-氢还原法与Ni和Ni/Co混合,分别标记为WC-Ni、WC-Ni/Co、WC-Ni和WC-Ni/Co。在真空中致密化后,化学沉淀法制备的样品的密度和晶粒尺寸比电化学沉积法制备的更致密、更细。同时,WC-Ni/Co由于WC和粘结相的均匀分布以及Ni-Co合金的固溶强化,获得了更好的力学性能,弯曲强度为1110MPa,冲击韧性为33kJ/m。此外,由于Ni-Co-P合金的存在,WC-Ni在3.5wt%NaCl溶液中获得了最低的自腐蚀电流密度8.17×10 A·cm,自腐蚀电位为-0.25V,最大耐蚀性为1.26×10 Ω。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/769c/10004337/fb27844cf1ed/materials-16-01977-g001.jpg

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