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基于回收利用操作中聚对苯二甲酸乙二酯的环境可持续水泥砂浆

Environmental Sustainable Cement Mortars Based on Polyethylene Terephthalate from Recycling Operations.

作者信息

Todaro Francesco, Petrella Andrea, Santomasi Giusy, De Gisi Sabino, Notarnicola Michele

机构信息

Department of Civil, Environmental, Land, Building Engineering and Chemistry (DICATECh), Polytechnic University of Bari, Via E. Orabona n. 4, 70125 Bari, Italy.

出版信息

Materials (Basel). 2023 Mar 6;16(5):2111. doi: 10.3390/ma16052111.

Abstract

The building and construction industry is a key sector behind the ecological transition in that it is one of the main responsible factors in the consumption of natural resources. Thus, in line with circular economy, the use of waste aggregates in mortars is a possible solution to increase the sustainability of cement materials. In the present paper, polyethylene terephthalate (PET) from bottle scraps (without chemical pretreatment) was used as aggregate in cement mortars to replace conventional sand aggregate (20%, 50% and 80% by weight). The fresh and hardened properties of the innovative mixtures proposed were evaluated through a multiscale physical-mechanical investigation. The main results of this study show the feasibility of the reuse of PET waste aggregates as substitutes for natural aggregates in mortars. The mixtures with bare PET resulted in less fluid than the specimens with sand; this was ascribed to the higher volume of the recycled aggregates with respect to sand. Moreover, PET mortars showed a high tensile strength and energy absorption capacity (with Rf = 1.9 ÷ 3.3 MPa, Rc = 6 ÷ 13 MPa); instead, sand samples were characterized by a brittle rupture. The lightweight specimens showed a thermal insulation increase ranging 65-84% with respect to the reference; the best results were obtained with 800 g of PET aggregate, characterized by a decrease in conductivity of approximately 86% concerning the control. The properties of these environmentally sustainable composite materials may be suitable for non-structural insulating artifacts.

摘要

建筑行业是生态转型背后的关键领域,因为它是自然资源消耗的主要责任因素之一。因此,根据循环经济理念,在砂浆中使用废弃骨料是提高水泥材料可持续性的一种可能解决方案。在本文中,来自瓶片的聚对苯二甲酸乙二酯(PET)(未经化学预处理)被用作水泥砂浆中的骨料,以替代传统砂骨料(按重量计分别为20%、50%和80%)。通过多尺度物理力学研究评估了所提出的创新混合物的新拌性能和硬化性能。本研究的主要结果表明,PET废弃骨料作为砂浆中天然骨料替代品再利用的可行性。含有裸PET的混合物比含砂试件的流动性小;这归因于再生骨料相对于砂的体积更大。此外,PET砂浆表现出较高的抗拉强度和能量吸收能力(Rf = 1.9÷3.3兆帕,Rc = 6÷13兆帕);相反,砂样的特点是脆性断裂。轻质试件的隔热性能相对于参考试件提高了65 - 84%;使用800克PET骨料获得了最佳结果,其电导率相对于对照降低了约86%。这些环境可持续复合材料的性能可能适用于非结构保温制品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce80/10004574/a61e7a1c11d5/materials-16-02111-g001.jpg

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