Suppr超能文献

考虑砂的预热至室温比、硅酸钠与氢氧化钠比以及粉煤灰与粒化高炉矿渣比的快硬地质聚合物材料力学性能研究

Investigation of the Mechanical Properties of Quick-Strength Geopolymer Material Considering Preheated-to-Room Temperature Ratio of Sand, NaSiO-to-NaOH Ratio, and Fly Ash-to-GGBS Ratio.

作者信息

Bhina Mohammad Rizwan, Liu Kuang-Yen, Hu John-Eric Hsin-Yu, Tsai Chih-Ta

机构信息

Department of Civil Engineering, National Cheng Kung University, Tainan 70101, Taiwan.

Sustainable Environment Research Laboratories (SERL), National Cheng Kung University, No. 500, Sec. 3, An-Ming Road, Annan District, Tainan 709015, Taiwan.

出版信息

Polymers (Basel). 2023 Feb 21;15(5):1084. doi: 10.3390/polym15051084.

Abstract

Geopolymer concrete is a useful alternative construction material for bridge deck systems, as it is characterized by a low carbon footprint, rapid setting, quick strength development, low cost, freeze-thaw resistance, low shrinkage, and sulphate and corrosion resistance. Heat curing enhances the mechanical properties of geopolymer materials (GPM), but it is not suitable for large structures, as it affects construction activities and increases energy consumption. Therefore, this study investigated the effect of preheated sand at varying temperatures on GPM compressive strength (Cs), the influence of NaSiO (sodium silicate)-to-NaOH (sodium hydroxide-10 molar concentration), and fly ash-to-granulated blast furnace slag (GGBS) ratios on the workability, setting time, and mechanical strength properties of high-performance GPM. The results indicate that a mix design with preheated sand improved the Cs of the GPM compared to sand at room temperature (25 ± 2 °C). This was caused by the heat energy increasing the kinetics of the polymerization reaction under similar curing conditions and with a similar curing period and fly ash-to-GGBS quantity. Additionally, 110 °C was shown to be the optimal preheated sand temperature in terms of enhancing the Cs of the GPM. A Cs of 52.56 MPa was achieved after three hours of hot oven curing at a constant temperature of 50 °C. GGBS in the geopolymer paste increased the mechanical and microstructure properties of the GPM as a result of different formations of crystalline calcium silicate (C-S-H) gel. The synthesis of C-S-H and amorphous gel in the NaSiO (SS) and NaOH (SH) solution increased the Cs of the GPM. We conclude that a NaSiO-to-NaOH ratio (SS-to-SH) of 5% was optimal in terms of enhancing the Cs of the GPM for sand preheated at 110 °C. Additionally, as the quantity of ground GGBS in the geopolymer paste increased, the thermal resistance of the GPM was significantly reduced.

摘要

地聚合物混凝土是桥面系统一种有用的替代建筑材料,其特点是碳足迹低、凝结快、强度发展迅速、成本低、抗冻融、收缩率低以及抗硫酸盐和耐腐蚀。热养护可提高地聚合物材料(GPM)的力学性能,但它不适用于大型结构,因为它会影响施工活动并增加能源消耗。因此,本研究调查了不同温度下预热砂对GPM抗压强度(Cs)的影响、硅酸钠(NaSiO)与氢氧化钠(NaOH,10摩尔浓度)的比例以及粉煤灰与粒化高炉矿渣(GGBS)的比例对高性能GPM的工作性、凝结时间和力学强度性能的影响。结果表明,与室温(25±2°C)下的砂相比,采用预热砂的配合比设计提高了GPM的Cs。这是由于在相似的养护条件、相似的养护期以及粉煤灰与GGBS用量的情况下,热能增加了聚合反应的动力学。此外,就提高GPM的Cs而言,110°C被证明是预热砂的最佳温度。在50°C恒温下热烘箱养护三小时后,Cs达到52.56MPa。地聚合物浆体中的GGBS由于结晶硅酸钙(C-S-H)凝胶的不同形成而提高了GPM的力学和微观结构性能。NaSiO(SS)和NaOH(SH)溶液中C-S-H和无定形凝胶的合成提高了GPM的Cs。我们得出结论,就提高110°C预热砂的GPM的Cs而言,NaSiO与NaOH的比例(SS与SH)为5%是最佳的。此外,随着地聚合物浆体中磨细GGBS用量的增加,GPM的热阻显著降低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db2c/10007510/b3314d1af65c/polymers-15-01084-g001.jpg

文献AI研究员

20分钟写一篇综述,助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型,支持多种主流文档格式。

立即体验