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实验室中聚合物固化与生物固化粉煤灰固化特性的比较

Comparison of Solidification Characteristics between Polymer-Cured and Bio-Cured Fly Ash in the Laboratory.

作者信息

Jia Yinggang, Liu Yuhan, Chen Jian

机构信息

School of Engineering and Technology, China University of Geosciences, Beijing 100083, China.

Key Laboratory of Luminescence Analysis and Molecular Sensing (Southwest University), Ministry of Education, College of Chemistry and Chemical Engineering, Southwest University, No. 2 Tiansheng Road, Beibei, Chongqing 400715, China.

出版信息

Polymers (Basel). 2023 Feb 23;15(5):1107. doi: 10.3390/polym15051107.

Abstract

Fly ash (FA) usually causes air and soil pollution due to wind erosion. However, most FA field surface stabilization technologies have long construction periods, poor curing effects, and secondary pollution. Therefore, there is an urgent need to develop an efficient and environmentally friendly curing technology. Polyacrylamide (PAM) is an environmental macromolecular chemical material for soil improvement, and Enzyme Induced Carbonate Precipitation (EICP) is a new friendly bio-reinforced soil technology. This study attempted to use chemical, biological, and chemical-biological composite treatment solutions to solidify FA, and the curing effect was evaluated by testing indicators, such as unconfined compressive strength (UCS), wind erosion rate (WER), and agglomerate particle size. The results showed that due to the viscosity increase in the treatment solution, with the increase in PAM concentration, the UCS of the cured samples increased first (from 41.3 kPa to 376.1 kPa) and then decreased slightly (from 376.1 kPa to 367.3 kPa), while the wind erosion rate of the cured samples decreased first (from 39.567 mg/(m·min) to 3.014 mg/(m·min)) and then increased slightly (from 3.014 mg/(m·min) to 3.427 mg/(m·min)). Scanning electron microscopy (SEM) indicated that the network structure formed by PAM between the FA particles improved the physical structure of the sample. On the other hand, PAM increased the nucleation sites for EICP. Due to the stable and dense spatial structure formed by the "bridging" effect of PAM and the cementation of CaCO crystals, the mechanical strength, wind erosion resistance, water stability, and frost resistance of the samples cured by PAM-EICP were increased significantly. The research will provide curing application experience and a theoretical basis for FA in wind erosion areas.

摘要

粉煤灰(FA)通常会因风蚀而造成空气和土壤污染。然而,大多数粉煤灰现场表面稳定化技术施工周期长、固化效果差且存在二次污染。因此,迫切需要开发一种高效且环保的固化技术。聚丙烯酰胺(PAM)是一种用于土壤改良的环境高分子化学材料,酶诱导碳酸盐沉淀(EICP)是一种新型的友好型生物加固土壤技术。本研究尝试采用化学、生物以及化学 - 生物复合处理方案来固化粉煤灰,并通过无侧限抗压强度(UCS)、风蚀率(WER)和团聚体粒径等测试指标来评估固化效果。结果表明,由于处理溶液粘度增加,随着PAM浓度的增加,固化样品的UCS先升高(从41.3 kPa升至376.1 kPa),然后略有下降(从376.1 kPa降至367.3 kPa),而固化样品的风蚀率先降低(从39.567 mg/(m·min)降至3.014 mg/(m·min)),然后略有上升(从3.014 mg/(m·min)升至3.427 mg/(m·min))。扫描电子显微镜(SEM)表明,PAM在粉煤灰颗粒之间形成的网络结构改善了样品的物理结构。另一方面,PAM增加了EICP的成核位点。由于PAM的“桥接”作用形成的稳定致密空间结构以及CaCO晶体的胶结作用,PAM - EICP固化样品的机械强度、抗风蚀性、水稳定性和抗冻性显著提高。该研究将为风蚀地区粉煤灰的固化应用提供经验和理论依据。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2e0b/10007492/d5797b45c120/polymers-15-01107-g001.jpg

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