Comparative assessment of formation pathways and adsorption behavior reveals the role of NaOH of MgO-modified diatomite on phosphate recovery.

The phosphate adsorption behavior on MgO-modified diatomite has been routinely investigated. Batch experiments tend to show that the addition of NaOH during preparation largely promoted adsorption performance, but comparative studies of MgO-modified diatomite with and without NaOH (MODH and MOD) based on morphology, composition, functional groups, isoelectric points and adsorption behavior have not been reported. We demonstrated that NaOH can etch the structure of MODH and promote the migration of phosphate to active sites, which allowed MODH to have a faster adsorption rate, superior environmental adaptability, adsorption selectivity and regeneration performance. The phosphate adsorption ability was enhanced from 96.73 (MOD) to 197.4 mg P/g (MODH) under optimum conditions. Furthermore, the partially hydrolyzed Si-OH group reacted with Mg-OH via a hydrolytic condensation reaction to form a new Si-O-Mg bond. Intraparticle diffusion, electrostatic attraction and surface complexation may be the main modes of phosphate adsorption by MOD, while the MODH surface mainly relied on the synergy of chemical precipitation and electrostatic attraction due to the abundant MgO adsorptive sites. Indeed, the present study provides a new understanding of the microscopic analysis of sample differences.