Porous MgO-modified biochar adsorbents fabricated by the activation of Mg(NO) for phosphate removal: Synergistic enhancement of porosity and active sites.

Engineering magnesium oxide (MgO)-modified biochar (MgO-biochar) with high porosity and active MgO load is a feasible pathway to enhance phosphate adsorption capacity. However, the blockage to pores caused by MgO particles is ubiquitous during the preparation, which seriously impaired the enhancement in adsorption performance. In this research, with the intent to enhance phosphate adsorption, an in-situ activation method based on Mg(NO)-activated pyrolysis technology was developed to fabricate MgO-biochar adsorbents with abundant fine pores and active sites simultaneously. The SEM image revealed that the tailor-made adsorbent has well-developed porous structure and abundant fluffy MgO active sites. Its maximum phosphate adsorption capacity was coming up to 1809 mg/g. The phosphate adsorption isotherms are in accordance well with the Langmuir model. The kinetic data, which agreed with the pseudo-second-order model, indicated that chemical interaction is existing between phosphate and MgO active sites. This work verified that the phosphate adsorption mechanism on MgO-biochar was composed of protonation, electrostatic attraction, monodentate complexation and bidentate complexation. In general, the facile in-situ activation method using Mg(NO) pyrolysis illuminated biochar activation with fine pores and highly efficient adsorption sites for efficient wastewater treatment.