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关于用于生物能源的大绿柄桑(Schizolobium parahyba var. amazonicum(Huber ex Ducke)Barneby)木材密度和微量元素变异性的线索。

Clues about wood density and trace-element variability of Schizolobium parahyba var. amazonicum (Huber ex Ducke) Barneby for bioenergy use.

机构信息

Departamento de Ciências Florestais e da Madeira, Universidade Federal do Espírito Santo (UFES). Av. Governador Lindemberg, Jerônimo Monteiro, ES, 31629550-000, Brazil.

Departamento de Ciências Florestais, Universidade de São Paulo (USP), Escola Superior de Agricultura Luiz de Queiroz, Av. Pádua Dias N° 11, Piracicaba, São Paulo, 13418-900, Brazil.

出版信息

Environ Sci Pollut Res Int. 2023 Apr;30(19):56161-56173. doi: 10.1007/s11356-023-26343-4. Epub 2023 Mar 14.

DOI:10.1007/s11356-023-26343-4
PMID:36917377
Abstract

The interest of biofuel producers in Neotropical species that have high growth rates, slight wood density variability, and elemental composition that does not compromise the environment has increased in recent decades. We investigated the density and chemical characteristics of wood of Schizolobium parahyba var. amazonicum (Huber × Ducke) Barneby as a source for the generation of bioenergy. Apparent radial wood density profiles (X-ray densitometry (XRD)) and the elemental distribution (X-ray fluorescence (XRF)) of Cl, S, K, and Ca in the wood of nine S. parahyba var. amazonicum trees, divided into three diameter classes (I = 15.5, II = 19.5, and III = 23.5 cm) were analyzed. The high heating value (HHV) of the wood samples was determined, and the energy density was estimated by the product of the HHV and the apparent density. Trees that grew better (classes II and III) produced wood with higher density. These trees showed higher concentrations of K and S, and lower concentrations of Ca and Cl. The highest Cl concentrations were observed in classes with smaller diameters. The chlorine levels met the standards for use of this wood as fuel, but the sulfur levels were higher than the threshold recommended by the ISO 17225-3:2021 guidelines, which can limit the use of the species for certain energy uses. The wood of S. parahyba var. amazonicum had interesting characteristics for the production of bioenergy due to its low density, so it can be used in the production of solid biofuels such as pellets and briquettes. Monitoring chlorine and sulfur is important, since during the combustion of biomass they are released into the atmosphere and can negatively contribute to the effects of climate change.

摘要

近几十年来,生物燃料生产商对生长速度快、木材密度变化小、元素组成不影响环境的新热带物种的兴趣日益增加。我们研究了 Schizolobium parahyba var. amazonicum(Huber × Ducke)Barneby 的木材密度和化学特性,作为生物能源的来源。对 9 棵 Schizolobium parahyba var. amazonicum 树木的木材进行了表观径向木材密度剖面(X 射线密度测定法(XRD))和 Cl、S、K 和 Ca 的元素分布(X 射线荧光(XRF))分析,将树木分为 3 个直径类(I=15.5、II=19.5 和 III=23.5 cm)。测定了木材样品的高位发热量(HHV),并通过 HHV 与表观密度的乘积估算了能量密度。生长较好的树木(II 类和 III 类)产生的木材密度更高。这些树木的 K 和 S 浓度较高,Ca 和 Cl 浓度较低。Cl 浓度最高的是直径较小的类。氯含量符合将这种木材用作燃料的标准,但硫含量高于 ISO 17225-3:2021 指南推荐的阈值,这可能会限制该物种在某些能源用途中的使用。由于 S. parahyba var. amazonicum 木材的密度较低,具有生产生物能源的有趣特性,因此可用于生产颗粒和压块等固体生物燃料。监测氯和硫很重要,因为在生物质燃烧过程中,它们会释放到大气中,并可能对气候变化的影响产生负面影响。

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