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纯1-(2-羟乙基)吡咯烷、3-氨基-1-丙醇、水及其混合物在293.15至363.15K和大气压下的密度与粘度

Densities, Viscosities of Pure 1-(2-Hydroxyethyl) Pyrrolidine, 3-Amino-1-Propanol, Water, and Their Mixtures at 293.15 to 363.15 K and Atmospheric Pressure.

作者信息

Hartono Ardi, Knuutila Hanna K

机构信息

Department of Chemical Engineering, University of Science and Technology, N-7491 Trondheim, Norway.

出版信息

J Chem Eng Data. 2023 Feb 23;68(3):525-535. doi: 10.1021/acs.jced.2c00648. eCollection 2023 Mar 9.

DOI:10.1021/acs.jced.2c00648
PMID:36930776
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10009753/
Abstract

Densities and viscosities of pure 1-(2-hydroxyethyl) pyrrolidine, 3-amino-1-propanol, water, and their blends' data are reported from 293.15 to 363.15 K and at ambient pressure. Densities of pure water show higher values than that of 3-amino-1-propanol and 1-(2-hydroxyethyl) pyrrolidine, whereas pure 3A1P is more viscous than 1-(2-hydroxyethyl) pyrrolidine and water. The excess molar volumes and viscosity deviations from the data are correlated to the Redlich-Kister equation. The shape and value for the excess molar volumes and viscosity deviations could explain the intermolecular interaction between the molecules.

摘要

报道了纯1-(2-羟乙基)吡咯烷、3-氨基-1-丙醇、水及其混合物在293.15至363.15 K以及常压下的密度和粘度数据。纯水的密度高于3-氨基-1-丙醇和1-(2-羟乙基)吡咯烷的密度，而纯3-氨基-1-丙醇比1-(2-羟乙基)吡咯烷和水更具粘性。根据这些数据计算得到的过量摩尔体积和粘度偏差与Redlich-Kister方程相关联。过量摩尔体积和粘度偏差的形状和数值可以解释分子间的相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/5e188caea290/je2c00648_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/f1771854eb68/je2c00648_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/e1c366599531/je2c00648_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/0ac8856f2bef/je2c00648_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/6fce37630efb/je2c00648_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/04eb59119367/je2c00648_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/5e188caea290/je2c00648_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/f1771854eb68/je2c00648_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/e1c366599531/je2c00648_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/0ac8856f2bef/je2c00648_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/6fce37630efb/je2c00648_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/04eb59119367/je2c00648_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c87/10009753/5e188caea290/je2c00648_0007.jpg

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本文引用的文献

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