College of Geology and Environment, Xi'an University of Science and Technology, Xi'an, 710054, China.
Research Institute of Coal Green Mining Geology, Xi'an University of Science and Technology, Xi'an, 710054, China.
Environ Geochem Health. 2023 Oct;45(10):7215-7236. doi: 10.1007/s10653-023-01530-x. Epub 2023 Mar 18.
The pollution of heavy metals in soil caused by exposed coal gangue and its prevention and control has become a hot issue restricting the green mining of coal in China. Nemerow integrated pollution index (NIPI), potential ecological risk index (RI) and human health risk assessment model were used to evaluate the pollution and risk of heavy metals (Cu, Cr, As, Pb) in the soil around the typical coal gangue hill in Fengfeng mining area of China. The results show that: firstly, the accumulation of coal gangue leads to the enrichment of four heavy metals in the surrounding shallow soil, and NIPI and RI were 1.0-4.4 and 21.63-91.28, respectively. The comprehensive pollution level of heavy metals in soil reached the warning line and above, and the potential ecological risk level reached slightly and above. When the horizontal distance exceeded 300 m, 300 m and 200 m, respectively, the influence of coal gangue hill on the heavy metal content in shallow soil, the comprehensive pollution level of heavy metals and the potential ecological risk level basically disappeared. In addition, based on the potential ecological risk assessment results and main risk factors, the ecological risk configuration of the study area was divided into five categories: "strong ecological risk + As," "intermediate ecological risk + As + Cu," "intermediate ecological risk + As + Cu or Pb," "minor ecological risk + As + Cu" and "minor ecological risk + As + Cu or Pb." The hazard index (HI) and total carcinogenic risk (TCR) of shallow soil polluted by heavy metals in the study area were 0.24-1.07 and 0.41 × 10-1.78 × 10, respectively, which posed non-carcinogenic and carcinogenic risks to children, but the risks were controllable. This study will help to take strategic measures to accurately control and repair the heavy metal pollution in the soil around the coal gangue hill and provide a scientific basis for solving the safe use of agricultural land and realizing the construction of ecological civilization.
煤矸石山暴露导致土壤重金属污染及其防治已成为制约中国绿色采煤的热点问题。采用内梅罗综合污染指数(NIPI)、潜在生态风险指数(RI)和人体健康风险评估模型,对中国峰峰矿区典型煤矸石山周围土壤中重金属(Cu、Cr、As、Pb)的污染和风险进行了评价。结果表明:首先,煤矸石的堆积导致周边浅层土壤中四种重金属的富集,NIPI 和 RI 分别为 1.0-4.4 和 21.63-91.28,土壤重金属综合污染水平达到警戒线及以上,潜在生态风险水平达到轻度及以上。当水平距离分别超过 300m、300m 和 200m 时,煤矸石山对浅层土壤重金属含量、重金属综合污染水平和潜在生态风险水平的影响基本消失。此外,基于潜在生态风险评价结果和主要风险因素,将研究区生态风险配置分为五类:“强生态风险+As”、“中生态风险+As+Cu”、“中生态风险+As+Cu 或 Pb”、“小生态风险+As+Cu”和“小生态风险+As+Cu 或 Pb”。研究区受重金属污染的浅层土壤危害指数(HI)和总致癌风险(TCR)分别为 0.24-1.07 和 0.41×10-1.78×10-1,对儿童具有非致癌和致癌风险,但风险是可控的。本研究将有助于采取战略措施,准确控制和修复煤矸石山周围土壤中的重金属污染,为解决农用地安全利用和实现生态文明建设提供科学依据。